Advanced Organic ChemistryThis survey of advanced chemistry covers virtually all the useful reactions--600 all told--with the scope, limitations, and mechanism of each described in detail. Extensive general sections on the mechanisms of the important reaction types, and five chapters on the structure and stereochemistry of organic compounds and reactive intermediates are included as well. Of the more than 10,000 references included, 5,000 are new in this edition. |
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Contents
Localized Chemical Bonding | 7 |
Delocalized Chemical Bonding | 25 |
Bonding Weaker than Covalent | 71 |
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acetic acid active acyl addition alcohols aldehydes alkyl allylic amines Angew aromatic aryl atom attack base bromine Brown Bull called carbon carboxylic carried catalyst cation Chapter charge Chem Chemistry Chim chloride Commun complex compounds containing converted discussion double bond effect electrons electrophilic energy Engl enol esters ethers evidence example followed formation formed free-radical give halides halogen hydrogen increase intermediate involves ketones known leaving group less mechanism metal method mixture molecule nucleophilic obtained Olah olefins orbitals Organic oxygen pair Perkin Trans Phys position possible prepared presence primary proton radicals reaction reactivity reagents rearrangement reduced resonance ring salts secondary shown side similar solution solvent species stable step structure substitution substrate Synthesis Table take place tertiary Tetrahedron Lett treated treatment usually values Wiley yields York