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assuming binary block copolymers broken line chain Chem compatible Composition dependence contribution corresponding crystalline crystallization decrease density derived effective conductivity elastic enthalpy entropy equation equilibrium estimated excess experimental data filled polymers filled samples filler content filler particles free energy function Gibbs free energy glass transition temperature heat capacity heat conductivity homopolymers inclusions increase interactions interface isotactic Kiev kinetics latter lattice layers linear Lipatov Yu liquid lower bounds Macromolecules microphase modulus molecular morphology nucleation observed obtained oligomers parameters percolation percolation threshold phase separation physical PMMA poly(ethylene poly(methyl methacrylate polymer blends polymer melt Polymer Phys Polymer Sci polymer systems polymeric polystyrene polyurethane predictions pressure Privalko V. P. properties pure polymer quantities relaxation respectively segments single-phase solid line specific volume spherulite spinodal spinodal decomposition structure surface temperature interval tensor theoretical thermodynamic thickness values viscosity Vysokomol Young's modulus Zhurn