Cationic Graft CopolymerizationJoseph Paul Kennedy |
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Contents
A Critical Overview | 1 |
Synthesis Characterization and Physical Properties of Polyvinyl chlo | 73 |
Synthesis and Characterization | 91 |
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1,2-dichloroethane acetone addition AlCl3 alkylaluminum compounds allyl Applied Polymer backbone carbenium ion cationic grafting CH₂ chain transfer characterization Chem chlorine Cl-IIR Cl-IIR-g-PSt coinitiator composition concentration containing copolymerization degradation dehydrochlorination determined dissolved Dreyfuss effect elution epoxide Et2AICI Et3Al experimental extraction films g/mole gelation Geon graft copolymer grafting efficiencies grafting experiments halide heptane high molecular weight homogeneous homopolymer homopolymerization Hypalon increasing initiation insoluble intrinsic viscosity isobutylene isobutylene conversion J. P. Kennedy kg/cm² Lewis acids Me3Al methanol methylene chloride mixture model epoxides modulus molecular weight distribution monomer n-pentane neoprene Nordel obtained olefins oxide oxonium ion pentane phase PIB branches polarity polyisobutylene Polymer Science polystyrene precipitation prepared presence PSt content PTHF Content pure graft PVC-g-PIB PVC-g-PIB/PVC blends PVC-g-PSt reaction rubber samples soluble solvent stress-strain studies styrene synthesis Table temperature tensile transfer to monomer U. S. patent ungrafted PVC weight fraction