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3 The Superposition Principle of Boltzmann
Experimental Tests of the Superposition Principle
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Acetate Filament amorphous application of load applied at zero assume bakelite balance arm Boltzmann carried cellulose chains computed consider constant deformation constant load corresponding creep and creep creep and recovery creep behavior creep recovery creep test creep under constant crystalline dashpot deformation due delayed elasticity diagram dielectric effect energy of activation fibers filamentous materials given grams hard rubber high polymers Hooke's Law increase instantaneous deformation investigation Kohlrausch length load application logarithmic logarithmic scale Long-Duration Tests Maxwell units mechanically conditioned micelles mins minutes model of Fig nylon filament obeys the Superposition observed obtained plastics plotted primary creep properties rayon recovery following recovery test relative delayed deformations relative humidity removal of load represents residual deformation residual torque scale factors secondary bonds Series shown in Fig specimen standard conditions strain stress structure Superposition Principle superposition test Table temperature textile tion total-deformation curves typical tests Viscose I Filament X-ray