Elemental Sulfur and Sulfur-Rich Compounds IRalf Steudel R. Steudel, B. Eckert: Solid Sulfur Allotropes.- R. Steudel: Liquid Sulfur.- R. Steudel, Y. Steudel, M.W. Wong: Speciation and Thermodynamics of Sulfur Vapor.- I. Krossing: Homoatomic Sulfur Cations.- R. Steudel: Aqueous Sulfur Sols.- W.E. Kleinjan, A. de Keizer, A. J. H. Janssen: Biologically Produced Sulfur. |
Contents
Solid Sulfur Allotropes | 3 |
Monoclinic | 35 |
2nd Fibrous and Laminar Sulfur S1 and | 45 |
3 | 52 |
4 | 59 |
HighPressure HighTemperature Phases p20 GPa T300 K | 67 |
Allotropes Consisting of Long Sulfur Chains | 68 |
QuantumChemical Calculations of SulfurRich Compounds | 74 |
13 | 99 |
16 | 110 |
R Steudel B Eckert 1 | 114 |
SpringerVerlag Berlin Heidelberg 2003 | 117 |
Homoatomic Sulfur Cations | 135 |
Aqueous Sulfur Sols | 153 |
Biologically Produced Sulfur | 166 |
| 198 | |
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Common terms and phrases
a-Sg absorption Allg amorphous Angew Anorg aqueous bacteria biologically produced sulfur bond angles bond lengths C₂ calculated carbon disulfide Chem chemical Chemotrophic compound oxidizing bacteria concentration crystal structure crystalline density dissociation electron elemental sulfur energy enthalpy experimental fibrous sulfur formation forms helices helix high-pressure hydrogen sulfide hydrophilic Inorg intermolecular isomers kJ mol-¹ laser liquid sulfur mixture mol¹ molecular structure molecular symmetry molecules monoclinic Naturforsch observed obtained orthorhombic particles Phys polymer polymer content polymeric sulfur polythionates prepared pressure quenched sulfur melts radicals Raman spectra range reaction reported room temperature sample Sg rings Sg2+ solid sulfur soluble solution solvent space group species spectroscopy stable Steudel studies sulfide sulfur allotropes sulfur atoms sulfur cations sulfur chains sulfur compound oxidizing sulfur globules sulfur rings sulfur sols sulfur vapor symmetry Table thermodynamic tion torsion angles Tuinstra unit cell values viscosity X-ray diffraction