Block Polymers: Proceedings of the Symposium on Block Polymers at the Meeting of the American Chemical Society in New York City in September 1969S. L. Aggarwal Block polymers represent another milestone in the preparation of polymers of controlled structure. Catalysts and polymerization methods that allowed the preparation of polymers in which the stereo- and geometric isomerism of the monomer units could be con trolled have indeed been among the major developments in polymer science during the last decade. The synthesis of block polymers, in which the sequence length of the comonomer units can be con trolled, portends equally important developments in the science and technology of polymers. The papers collected in this volume cover primarily the pro ceedings of the most recent symposium on block polymers, sponsored by the Division of Polymer Chemistry of the American Chemical Society. It was held in New York City during the Society's 158th National Meeting in September, 1969. Additional contributions from selected authors were invited especially for this book to achieve the most up-to-date account of the advances that have been made since the development of the thermoplastic elastomers that first brought into focus this important area of research. The first two papers in this volume draw attention to the various problems that should be considered in the preparation of block polymers of precisely defined structure from styrene and butadiene or isoprene by anionic polymerization. Characterization of block polymers presents many problems and there is a paucity of systematic work in this area. Attention has been given to the di lute solution properties of block polymers,however, in one of the papers in this volume. |
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Results 1-3 of 25
Page 73
... B sequences in the system . This is demonstrated schematically in Fig . 12 , using the triangular phase diagram , in which the chain line indicates the isopleth keeping the total sequence ratio identical with that of the A - B type block ...
... B sequences in the system . This is demonstrated schematically in Fig . 12 , using the triangular phase diagram , in which the chain line indicates the isopleth keeping the total sequence ratio identical with that of the A - B type block ...
Page 74
... B type block copolymer , the polymerization process may be treated as similar to the solvent casting process in our experiments . Consider the process of cast- ing from a dilute solution , the three polymer solutes , A - B type block ...
... B type block copolymer , the polymerization process may be treated as similar to the solvent casting process in our experiments . Consider the process of cast- ing from a dilute solution , the three polymer solutes , A - B type block ...
Page 333
... Block polymers , AB type , domain formation mechanism , 53 , 54 domain formation , thermody- namic theory , 61 emulsifying effect of , 71 , 74 morphology of , 92 Block polymers , ABA type , tensile strength of , 145 time dependent ...
... Block polymers , AB type , domain formation mechanism , 53 , 54 domain formation , thermody- namic theory , 61 emulsifying effect of , 71 , 74 morphology of , 92 Block polymers , ABA type , tensile strength of , 145 time dependent ...
Contents
Problems in the Synthesis of Block Polymers | 1 |
Experimental | 11 |
Small Angle XRay Scattering Studies of TriBlock | 19 |
Copyright | |
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Common terms and phrases
A-B type block a-MST anionic annealing BCMO behavior benzene BG copolymers block copolymers BPAC butadiene carbanions catalyst Chem chemical colloidal component composition concentration copolymerization crystalline crystallization curves decrease diene domain structure elastomers electron micrographs ethylene oxide experimental Figure films cast formation fraction glass transition graft copolymers hard segments heat homopolymers increase initiation interactions isoprene Kraton lamellae lithium living ends matrix mechanical melting point micelle mixtures modulus mole molecular weight monomer morphology observed osmium tetroxide parameters particles phase separation phenyl ether plastic poly poly-THF polybutadiene polycarbonate polyisoprene Polymer Sci polymerization polystyrene polystyrene domains prepared properties PS-PEO reaction rubber samples scattering shear rate Skoulios sodium solubility solution solvent specimens spherical spherulitic strain stress stress-strain studies styrene styrene content styrene-butadiene styrene-isoprene subchains sulfide Table tensile strength thermal Thermolastic Tobolsky toluene transition temperature triblock type block copolymer urethane values viscosity x-ray