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adsorbed adsorbed layer adsorption aggregates AGreP applied aqueous arises attractive force behaviour Brownian motion bulk Chapter charged surface chemical potential Chemistry coagulation coalescence collision colloid science colloidal dispersions colloidal particles colloidal systems component constant contribution counter-ions decreases depends diffusion dilute discussion distance DLVO theory droplets effect electric field electrical potential electrolyte electrolyte concentration electrostatic emulsion energy barrier equation equilibrium example factors flocculation flocs flow foam formation free energy free-energy curve Gibbs given head groups hydrocarbon important increase interaction interface interparticle forces involves ionic ions leading light scattering liquid lower measurements micelle micellisation mole fraction molecular molecules monomer negatively charged osmotic phase plane plates polarised polymer pressure properties radius relative repulsive forces result rheological separation shear rate shown in Figure solid particles soluble solution solvent spherical particles stable steric stabilisation structure surface tension surfactant theory thickness thin tion vapour velocity viscosity volume Waals zero