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air craze applied stress behaviour bond brittle chain direction constant crack growth crack propagation crack tip crack velocity craze fibrils craze initiation craze surface craze tip cross-linked curve cycles damage zone decrease delamination diacetylene displacement effect elastic elastomers electron environment environmental craze epoxy resins experimental failure modes fatigue loading fibres fibrils fracture mechanics fracture surface fracture toughness frequency glass glass/epoxy impact strength impact tests increase laminates linear-elastic macroscopic materials matrix measured methanol modulus molecular fracture molecular weight molecules observed obtained occurs oriented parameter Phys plastic deformation plasticised plies PMMA poly(methylmethacrylate polyethylene polymer crystals Polymer Sci polymeric polyoxymethylene predicted residual strength rubber semicrystalline semicrystalline polymers shear shear stress shown in Fig shows single crystals solid specimen static stiffness strain rate stress intensity factor structure studies surface stress temperature tensile strength tensile stress test-piece thermoplastics thermosetting thickness tion unnotched