Solution Dynamics of Synthetic and Natural Polyelectrolytes |
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Page 84
... calculated , using the following equations : έ = txCp Ae X E0 ( A.1 ) ( A.2 ) E = ω Χ ΕΟ Ке = t Ae × Rp ( A.3 ) where t is the gap between the electrodes , Ae is the area of each electrode and w is the angular frequency ( w = 2πƒ ) ...
... calculated , using the following equations : έ = txCp Ae X E0 ( A.1 ) ( A.2 ) E = ω Χ ΕΟ Ке = t Ae × Rp ( A.3 ) where t is the gap between the electrodes , Ae is the area of each electrode and w is the angular frequency ( w = 2πƒ ) ...
Page 85
... calculated from Equation A.6 , and the conductivity calculated from Equation A.3 is shown in Figure A.3 . The conductivity sol of each solution was calculated for each concentration by averaging the data obtained from 0.075 to 0.5 MHz ...
... calculated from Equation A.6 , and the conductivity calculated from Equation A.3 is shown in Figure A.3 . The conductivity sol of each solution was calculated for each concentration by averaging the data obtained from 0.075 to 0.5 MHz ...
Page 91
... Calculated ( A from Am ) Calculated & ( A from A ) 10-2 10-1 100 Concentration ( M ) Fig . A.6 . The experimental correlation length & determined from SANS , as described in Chapter 2 , is compared to the theoretical prediction using A ...
... Calculated ( A from Am ) Calculated & ( A from A ) 10-2 10-1 100 Concentration ( M ) Fig . A.6 . The experimental correlation length & determined from SANS , as described in Chapter 2 , is compared to the theoretical prediction using A ...
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added salt adenosine albumin and y-globulins anti-inflammatory apparent viscosity Aspirin binding Bjerrum length BSA & globulins calculated chain length dependence Chapter Concentration dependence correlation length counterion condensation D)-penicillamine data for NaPAMS dependence of viscosity determined dielectric constant Dobrynin drugs effective charge electrostatic blob entangled solution entanglement concentration Equation experimental filled circles frequency function of shear Hyaluronan hyaluronic acid hydroxychloroquine ibuprofen interactions measured Methotrexate mg/mL NaHA molecular weight molecular weight samples NaPAMS Mw NaPAMS solutions NaPSS neutral polymers number of monomers open triangles osmotic pressure phosphate buffered saline polyelectrolyte chain polyelectrolyte solutions polyion polymer poor solvent regime Rheological data rheology Rinaudo scaling prediction scaling theories semidilute solution semidilute unentangled solution shear history shear rate Shear Rate s¹ shear thinning shown in Figure sodium hyaluronate specific conductance specific viscosity stainless steel Sulfasalazine synovial fluid model terminal modulus viscoelasticity viscosity data weak reversible gel Witten and Pincus