Solution Dynamics of Synthetic and Natural Polyelectrolytes |
From inside the book
Results 1-3 of 13
Page 13
... semidilute unentangled solution regime , relaxation time decreases with increasing concentration — a feature unique to polyelectrolyte solutions and reported previously [ 3.17 ] . In Figure 2.4 , 7 , and 7o are shown as a function of ...
... semidilute unentangled solution regime , relaxation time decreases with increasing concentration — a feature unique to polyelectrolyte solutions and reported previously [ 3.17 ] . In Figure 2.4 , 7 , and 7o are shown as a function of ...
Page 47
... semidilute unentangled c5 / 4 c 2Ac , semidilute unentangled c « c3 / 2 c 2Acs c » ( 4.1 ) semidilute entangled 15/4 ... solution , viscosity is predicted to scale with concentration ( 7sp ~ c1 ) for polyelectrolytes in the high salt limit ( ...
... semidilute unentangled c5 / 4 c 2Ac , semidilute unentangled c « c3 / 2 c 2Acs c » ( 4.1 ) semidilute entangled 15/4 ... solution , viscosity is predicted to scale with concentration ( 7sp ~ c1 ) for polyelectrolytes in the high salt limit ( ...
Page 48
... semidilute entangled solutions [ 1 ] . These data are in excellent agreement with the work done by Rinaudo , et al . [ 56 ] . 4.0 ... semidilute unentangled and entangled solution . polyelectrolyte solutions in the high salt limit are 48.
... semidilute entangled solutions [ 1 ] . These data are in excellent agreement with the work done by Rinaudo , et al . [ 56 ] . 4.0 ... semidilute unentangled and entangled solution . polyelectrolyte solutions in the high salt limit are 48.
Common terms and phrases
added salt adenosine albumin and y-globulins anti-inflammatory apparent viscosity Aspirin binding Bjerrum length BSA & globulins calculated chain length dependence Chapter Concentration dependence correlation length counterion condensation D)-penicillamine data for NaPAMS dependence of viscosity determined dielectric constant Dobrynin drugs effective charge electrostatic blob entangled solution entanglement concentration Equation experimental filled circles frequency function of shear Hyaluronan hyaluronic acid hydroxychloroquine ibuprofen interactions measured Methotrexate mg/mL NaHA molecular weight molecular weight samples NaPAMS Mw NaPAMS solutions NaPSS neutral polymers number of monomers open triangles osmotic pressure phosphate buffered saline polyelectrolyte chain polyelectrolyte solutions polyion polymer poor solvent regime Rheological data rheology Rinaudo scaling prediction scaling theories semidilute solution semidilute unentangled solution shear history shear rate Shear Rate s¹ shear thinning shown in Figure sodium hyaluronate specific conductance specific viscosity stainless steel Sulfasalazine synovial fluid model terminal modulus viscoelasticity viscosity data weak reversible gel Witten and Pincus