Step-growth Polymers for High-performance Materials: New Synthetic MethodsPresents the latest work in transition metal catalyzed polymerization, dendritic and hyperbranched systems, poly(aryl ether) synthesis, polyimides, and high-temperature polymers. Describes recent research on commercially important polymers based on step-growth polymerization. Includes well-referenced overview articles that review step-growth polymerization and indicate how individual research papers have impacted the field. |
Contents
StepPolymerization Reactions via Nickel | 2 |
From ArylX to ArylH Activation in MetalCatalyzed | 57 |
PalladiumCatalyzed Carbonylation Polymerizations | 73 |
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Common terms and phrases
13C NMR ¹H NMR acid activated adamantane aramids aromatic aryl aryl fluoride bisphenols Calcd carbon carboxylic catalyst catalyzed cation CH3 CH3 chain ends Chem chemical shift chemistry chloride compounds condensation copolymers cross-coupling dendrimers diamines dimers diol dL/g DMAC electron equation equiv ester Figure films flask formation functional groups glass transition temperatures H₂N heating Heck reaction Hedrick heterocycle high molecular weight hybrid hyperbranched macromolecules inherent viscosity ligand linear polymers Macromolecules Makromol mechanism mmol molecular weight monomers nitrogen NMR spectra nucleophilic obtained oligomers organic electrophiles oxidative addition palladium Pd-Gr Percec phenolic poly(aryl ether polyamides polycarbonates polycondensation polyesters polyethers polyformal polymerization polymers polyurethanes PPh3 prepared presence properties pyridine reaction mixture reactivity reflux resulting room temperature Scheme side reactions silica soluble solution solvent step-growth stirred structure substitution sulfone synthesis Table thermal stability thianthrene toluene triflates yield