Physics of Polymer Surfaces and InterfacesIsaac C. Sanchez Physics of Polymer Surfaces and Interfaces emphasizes current theoretical ideas and modern experimental tools for characterizing the physical properties of polymer surfaces and interfaces. Foremost are their important roles in polymer technology throughthe processes of wetting, adhesion, adsorption, and through their effect on the kinetics of phase separation and mechanical mixing of molten polymers. Each of the 14 chapters in this book stands as a 'mini-review' of a specific subject. This up-to-date compendium of the most significant theoretical and experimental works provides a scientific understanding of the physics of polymer interfaces and surfaces and will aid scientists in planning and interpreting new results. |
Contents
Density Functional Theories of Polymer Interfaces | 29 |
Mechanical Properties of Polymer Interfaces | 55 |
Molecular Modeling of Polymer Surfaces and PolymerSolid | 139 |
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adsorbed adsorption adsorption energy angle approximation average beam blends block copolymer bulk calculated capillary wave chain ends Chem chemical chromophore coefficient coil Colloid Interface Sci component concentration configurations contribution decay density profile dependence depth resolution deuterated deuterium diffusion distance distribution dynamics Equation experimental experiments factor film FRES Gennes glassy gradient homopolymer hydrogen incident increase integral interactions interdiffusion interfacial tension interphase isotropic lattice layer length scales loops Macromolecules matrix mean-field melt molecular weight molecules monolayers monomers neutron reflectivity neutron reflectometry nonlocal nuclear reaction analysis obtained parameters particles partition function phase Phys PMMA poly polymer polymer chains polymer interfaces polymerization polystyrene potential problem radius of gyration recoil reflectivity curve reflectometry region sample segments shown in Figure simulations solid solution solvent square-gradient statistical structure substrate surface tension technique temperature theoretical theory thermodynamic thickness tion values volume fraction width X-rays