Anionic Polymerization: Kinetics, Mechanisms, and Synthesis: Based on a Symposium Sponsored by the Division of Polymer Chemistry at the 179th Meeting of the American Chemical Society, March 24-28, 1980 |
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Contents
Current Status of Anionic Polymerization | 17 |
Synthesis of Controlled Polymer Structures | 41 |
Synthesis of Model Macromolecules of Various Types | 59 |
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Common terms and phrases
1981 American Chemical acrolein active centers addition aggregation anionic polymerization benzene block copolymers BuLi butadiene butyl Bywater carbanion carbon cation chain ends Chem complex compounds concentration copolymerization counterion cyclic decrease dianion diblock diene dimer dissociation DVB/RLi equilibrium ether Fetters Figure formation formed fraction functional hexane hydrocarbon increase initiator ionic isoprene isotactic kinetic linear lithium living ends living polymers loose ion pair MACROMER Macromolecules Makromol merization metalation methyl microstructure mole molecular weight distribution molecules monomer n-butyllithium naphthalene observed obtained oligomers organolithium oxidation peak polar poly polybutadiene polyisoprene polymer polystyrene potassium prepared propagation rate proton rate constants ratio reacted reaction reactivity Rubber salt shown Smid solution solvation solvent species spectra spectrum SrB2 SrS2 structure studied styrene synthesis Szwarc Table temperature termination tetrahydrofuran tion TMEDA toluene trans triblock triple ions TrMA values vinyl viscosity Worsfold