Mechanism in Organic Chemistry |
Contents
MECHANISM AND REACTIVITY | 1 |
Energies of Transition States | 11 |
Isotope Effects | 16 |
Copyright | |
34 other sections not shown
Common terms and phrases
acetic acetone acid addition allyl Amer anion aprotic solvents aqueous attack base bromide butadiene carbanion carbon atom carbonium ion catalysis cation Chem chemistry chloride compounds concerted conjugate correlation cycloaddition cyclobutene cyclopropane derivatives deuterium electrons electrophilic elimination reactions energy equation equilibrium ester ethanol EtOH example exchange factor favoured Figure formation formed free-energy free-energy relationships free-radical ground-state H H H H. C. Brown H₂O halides hydrogen hydrogen-bonding hydrolysis increase interactions intermediate inversion involved iodide ion-pair ionization isotope effect k₂ kcal kcal mole-¹ kinetic leaving group mechanism MeOH methyl methylene molecule non-bonded nucleophilic observed occur olefin optically active orbital oxygen Ph Ph phenyl polar proton proton-transfer racemization radical rate constant rate-determining ratio react reactants reaction rate reactivity reagent rearrangement relative ring SN2 reaction sodium solution solvation solvolysis sp² stability stereochemical steric steric effects structure studied substituent substitution substrate syn-elimination t-butyl Tetrahedron tosylate transition-state Winstein