High Temperature Vapors: Science and Technology |
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Page 11
... anion , e is the unit of electrostatic charge , r the internuclear separation of ions , and B , n are empirical constants representing repulsive interactions . For NaCl the calculated and experimental crystal energy is 184 kcal mol - 1 ...
... anion , e is the unit of electrostatic charge , r the internuclear separation of ions , and B , n are empirical constants representing repulsive interactions . For NaCl the calculated and experimental crystal energy is 184 kcal mol - 1 ...
Page 142
... anion - anion repulsion terms of the dimer potential energy are appreciable , being in the region of 100 kcal mol - 1 . The observed trend in the heats of formation of the cyclic ring- structured mixed dimers can be explained in terms ...
... anion - anion repulsion terms of the dimer potential energy are appreciable , being in the region of 100 kcal mol - 1 . The observed trend in the heats of formation of the cyclic ring- structured mixed dimers can be explained in terms ...
Page 143
... anion - anion interaction . In applying this correlation to hypothetical systems , one can usually make an a priori estimate of whether the dimeric species should be classified as mainly ionic or mainly covalent . It then appears ...
... anion - anion interaction . In applying this correlation to hypothetical systems , one can usually make an a priori estimate of whether the dimeric species should be classified as mainly ionic or mainly covalent . It then appears ...
Contents
Appendix Major Literature Sources for High Temperature Chemistry | 36 |
GraphiteGas Reactions | 59 |
Appendix Some Additional Recent Literature on High Temperature GasSolid | 89 |
Copyright | |
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addition alkali metal atoms basic bond dissociation energies Bulewicz calculated Chapter Chem chemical reaction chemical vapor deposition chemistry chloride combustion complex components composition concentration condensed considered corrosion determined diffusion flames discussion dissociation energies effect electron emission enthalpy entropy equilibrium constant example experimental fission fission products fluorides formation free energy fuel gases given H-atom H₂ H₂O halogen heat Hence high temperature species high temperature vapors hydroxide inhibition inhibitor interaction involving ionization ions kcal mol-¹ kinetic mass spectrometric materials metal halide metal oxide mole mole fraction molecular species NaCl nuclear fission observed oxide oxygen Padley partial pressure phase Phys plasma premixed premixed flames present production radical reactants reaction rates reaction zone reactor recent recombination reduced region relatively rocket Section solid solubility spectroscopic stability Sugden surface Symp Table techniques temperature thermal thermodynamic tion vapor deposition vapor species vapor-phase volatile York