High Temperature Vapors: Science and Technology |
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Page 71
... entropy change is also in accord with the entropy " rules " given in Chapter 3 , Section IV . For the analogous cases involving M ( OH ) , and M ( OH ) 4 , AS3 values of -3 and 2 cal deg1 mol - 1 , respec- tively , are similarly ...
... entropy change is also in accord with the entropy " rules " given in Chapter 3 , Section IV . For the analogous cases involving M ( OH ) , and M ( OH ) 4 , AS3 values of -3 and 2 cal deg1 mol - 1 , respec- tively , are similarly ...
Page 78
... entropy may be expressed in terms of a summation of entropy contributions from the individual molecular components , i.e. , Smolar = Σ ( 1 / n ) X ; S ; i where n is the number of molecules of H2O in species i , i.e. , 2 for dimer , 3 ...
... entropy may be expressed in terms of a summation of entropy contributions from the individual molecular components , i.e. , Smolar = Σ ( 1 / n ) X ; S ; i where n is the number of molecules of H2O in species i , i.e. , 2 for dimer , 3 ...
Page 81
... entropy for Si ( OH ) , as 108 ± 4 cal deg1 mol - 1 , by using the statistical method and estimated molecular constants . Hence , from the known entropy of SiO2 ( s ) ( JANAF , 1971 ) and the previously estimated entropy value of about ...
... entropy for Si ( OH ) , as 108 ± 4 cal deg1 mol - 1 , by using the statistical method and estimated molecular constants . Hence , from the known entropy of SiO2 ( s ) ( JANAF , 1971 ) and the previously estimated entropy value of about ...
Contents
Appendix Major Literature Sources for High Temperature Chemistry | 36 |
GraphiteGas Reactions | 59 |
Appendix Some Additional Recent Literature on High Temperature GasSolid | 89 |
Copyright | |
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addition alkali metal atoms basic bond dissociation energies Bulewicz calculated Chapter Chem chemical reaction chemical vapor deposition chemistry chloride combustion complex components composition concentration condensed considered corrosion determined diffusion flames discussion dissociation energies effect electron emission enthalpy entropy equilibrium constant example experimental fission fission products fluorides formation free energy fuel gases given H-atom H₂ H₂O halogen heat Hence high temperature species high temperature vapors hydroxide inhibition inhibitor interaction involving ionization ions kcal mol-¹ kinetic mass spectrometric materials metal halide metal oxide mole mole fraction molecular species NaCl nuclear fission observed oxide oxygen Padley partial pressure phase Phys plasma premixed premixed flames present production radical reactants reaction rates reaction zone reactor recent recombination reduced region relatively rocket Section solid solubility spectroscopic stability Sugden surface Symp Table techniques temperature thermal thermodynamic tion vapor deposition vapor species vapor-phase volatile York