High Temperature Vapors: Science and Technology |
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Page 30
... function . This function takes the form $ ( r ) = 4e [ ( a / r ) 12 ( a / r ) ® ] , - where r is the internuclear separation . For bimolecular collisions between unlike molecules the following approximations are used € 12 = ( € 162 ) 1 ...
... function . This function takes the form $ ( r ) = 4e [ ( a / r ) 12 ( a / r ) ® ] , - where r is the internuclear separation . For bimolecular collisions between unlike molecules the following approximations are used € 12 = ( € 162 ) 1 ...
Page 31
... function data are unavailable the following empirical relations are used : € / k = 0.77Tc = 1.157ь = 1.92Tm and σ = 0.841 ( V. ) 1/3 = 1.166 ( V ) 1/3 = 1.221 ( Vm ) 1/3 , where / k is in units of K , and V is the molar volume at the ...
... function data are unavailable the following empirical relations are used : € / k = 0.77Tc = 1.157ь = 1.92Tm and σ = 0.841 ( V. ) 1/3 = 1.166 ( V ) 1/3 = 1.221 ( Vm ) 1/3 , where / k is in units of K , and V is the molar volume at the ...
Page 105
... function of temperature . From these calculations it was possible to deduce the solubility of Si in the vapor phase and the weight of Si deposited as a function of temperature and initial reactant pressure . For the case where SiCl , is ...
... function of temperature . From these calculations it was possible to deduce the solubility of Si in the vapor phase and the weight of Si deposited as a function of temperature and initial reactant pressure . For the case where SiCl , is ...
Contents
Appendix Major Literature Sources for High Temperature Chemistry | 36 |
GraphiteGas Reactions | 59 |
Appendix Some Additional Recent Literature on High Temperature GasSolid | 89 |
Copyright | |
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addition alkali metal atoms basic bond dissociation energies Bulewicz calculated Chapter Chem chemical reaction chemical vapor deposition chemistry chloride combustion complex components composition concentration condensed considered corrosion determined diffusion flames discussion dissociation energies effect electron emission enthalpy entropy equilibrium constant example experimental fission fission products fluorides formation free energy fuel gases given H-atom H₂ H₂O halogen heat Hence high temperature species high temperature vapors hydroxide inhibition inhibitor interaction involving ionization ions kcal mol-¹ kinetic mass spectrometric materials metal halide metal oxide mole mole fraction molecular species NaCl nuclear fission observed oxide oxygen Padley partial pressure phase Phys plasma premixed premixed flames present production radical reactants reaction rates reaction zone reactor recent recombination reduced region relatively rocket Section solid solubility spectroscopic stability Sugden surface Symp Table techniques temperature thermal thermodynamic tion vapor deposition vapor species vapor-phase volatile York