High Temperature Vapors: Science and Technology |
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Page 339
... inhibition mechanism must involve an interaction between species containing either Cl or Br and a flame - propagating radical . Furthermore , either the halide species or the flame radical , or both , must contain a H- atom . Thus ...
... inhibition mechanism must involve an interaction between species containing either Cl or Br and a flame - propagating radical . Furthermore , either the halide species or the flame radical , or both , must contain a H- atom . Thus ...
Page 356
... inhibition by these elements . With this model , the reaction KOH + H → K + H2O is involved in a catalytic loss of H - atoms with resulting flame inhibition . There are several possible explanations for this apparent anomaly . First ...
... inhibition by these elements . With this model , the reaction KOH + H → K + H2O is involved in a catalytic loss of H - atoms with resulting flame inhibition . There are several possible explanations for this apparent anomaly . First ...
Page 357
... inhibition was ob- served . A factor - of - 2 reduction in the H - atom concentration was also observed when 10 - 3 mole fraction of TMP was added to the 1 - atm flame . Fenimore and Jones ( 1964 ) suggested that the lack of an ...
... inhibition was ob- served . A factor - of - 2 reduction in the H - atom concentration was also observed when 10 - 3 mole fraction of TMP was added to the 1 - atm flame . Fenimore and Jones ( 1964 ) suggested that the lack of an ...
Contents
Appendix Major Literature Sources for High Temperature Chemistry | 36 |
GraphiteGas Reactions | 59 |
Appendix Some Additional Recent Literature on High Temperature GasSolid | 89 |
Copyright | |
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addition alkali metal atoms basic bond dissociation energies Bulewicz calculated Chapter Chem chemical reaction chemical vapor deposition chemistry chloride combustion complex components composition concentration condensed considered corrosion determined diffusion flames discussion dissociation energies effect electron emission enthalpy entropy equilibrium constant example experimental fission fission products fluorides formation free energy fuel gases given H-atom H₂ H₂O halogen heat Hence high temperature species high temperature vapors hydroxide inhibition inhibitor interaction involving ionization ions kcal mol-¹ kinetic mass spectrometric materials metal halide metal oxide mole mole fraction molecular species NaCl nuclear fission observed oxide oxygen Padley partial pressure phase Phys plasma premixed premixed flames present production radical reactants reaction rates reaction zone reactor recent recombination reduced region relatively rocket Section solid solubility spectroscopic stability Sugden surface Symp Table techniques temperature thermal thermodynamic tion vapor deposition vapor species vapor-phase volatile York