High Temperature Vapors: Science and Technology |
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Page 11
... ionic in their bonding character and their stability can be expressed in terms of a crystal or lattice energy , i.e. , for an Na + Cl- type solid : U = N ( - Agig2e2 r Apigue2 + 2 ) . B pn where N is Avogadro's number , A the Madelung ...
... ionic in their bonding character and their stability can be expressed in terms of a crystal or lattice energy , i.e. , for an Na + Cl- type solid : U = N ( - Agig2e2 r Apigue2 + 2 ) . B pn where N is Avogadro's number , A the Madelung ...
Page 142
... ionic repulsion in the ring of the mixed - dimer species . According to the ionic model of bonding , which is known to apply reasonably well to alkali halide energetics , e.g. , see the review of Bauer and Porter ( 1964 ) , the cation ...
... ionic repulsion in the ring of the mixed - dimer species . According to the ionic model of bonding , which is known to apply reasonably well to alkali halide energetics , e.g. , see the review of Bauer and Porter ( 1964 ) , the cation ...
Page 143
... IONIC 20 NaLaCl CsSnCl3 KMgCl3 LIAI F4 Na Be F3 Na SnCl3 KSnF3 Na AIC 4 Na BeCl3 10 Cs SnBr3 TI InCI4 KSn 13 NaPbCl3 LICSCI2 COVALENT Rb CsCl2 2 3 4 1 REDUCTION IN CATION REPULSION -AU [ Å- ' ] 5 6 Fig . 3.6 Correlation of excess ...
... IONIC 20 NaLaCl CsSnCl3 KMgCl3 LIAI F4 Na Be F3 Na SnCl3 KSnF3 Na AIC 4 Na BeCl3 10 Cs SnBr3 TI InCI4 KSn 13 NaPbCl3 LICSCI2 COVALENT Rb CsCl2 2 3 4 1 REDUCTION IN CATION REPULSION -AU [ Å- ' ] 5 6 Fig . 3.6 Correlation of excess ...
Contents
Appendix Major Literature Sources for High Temperature Chemistry | 36 |
GraphiteGas Reactions | 59 |
Appendix Some Additional Recent Literature on High Temperature GasSolid | 89 |
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addition alkali metal atoms basic bond dissociation energies Bulewicz calculated Chapter Chem chemical reaction chemical vapor deposition chemistry chloride combustion complex components composition concentration condensed considered corrosion determined diffusion flames discussion dissociation energies effect electron emission enthalpy entropy equilibrium constant example experimental fission fission products fluorides formation free energy fuel gases given H-atom H₂ H₂O halogen heat Hence high temperature species high temperature vapors hydroxide inhibition inhibitor interaction involving ionization ions kcal mol-¹ kinetic mass spectrometric materials metal halide metal oxide mole mole fraction molecular species NaCl nuclear fission observed oxide oxygen Padley partial pressure phase Phys plasma premixed premixed flames present production radical reactants reaction rates reaction zone reactor recent recombination reduced region relatively rocket Section solid solubility spectroscopic stability Sugden surface Symp Table techniques temperature thermal thermodynamic tion vapor deposition vapor species vapor-phase volatile York