High Temperature Vapors: Science and Technology |
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Page 77
Science and Technology John W. Hastie. monomers , of 12.6 kcal mol - 1 . A more recent , and presumably more ac- curate , calculation by Morokuma and Winick ( 1970 ) gives a dimer sta- bility of 6.55 kcal mol - 1 . 4 Using molecular beam ...
Science and Technology John W. Hastie. monomers , of 12.6 kcal mol - 1 . A more recent , and presumably more ac- curate , calculation by Morokuma and Winick ( 1970 ) gives a dimer sta- bility of 6.55 kcal mol - 1 . 4 Using molecular beam ...
Page 84
... mol - 1 . Taking into account the known entropy of sublimation for NaCl , i.e. , ~ + 32 cal deg1 mol - 1 , the ... kcal mol - 1 and , as AH +5 kcal mol - 1 , it follows that AS1 = -23.5 cal deg1 mol - 1 which is basically in agreement ...
... mol - 1 . Taking into account the known entropy of sublimation for NaCl , i.e. , ~ + 32 cal deg1 mol - 1 , the ... kcal mol - 1 and , as AH +5 kcal mol - 1 , it follows that AS1 = -23.5 cal deg1 mol - 1 which is basically in agreement ...
Page 144
... ( kcal mol - 1 ) 44.5 ± 2 KCl + SrCl2 = KSrCl3 , 67 ± 17 KCl + LaCl3 = KLaCl4 , 614 KCl + ThCl = KThCl5 , 49 ± 3 . ( 1 ) ( 2 ) ( 3 ) ( 4 ) Consider the application of Rules 2 , 3 , and 4 to the above reactions . From the principles of ...
... ( kcal mol - 1 ) 44.5 ± 2 KCl + SrCl2 = KSrCl3 , 67 ± 17 KCl + LaCl3 = KLaCl4 , 614 KCl + ThCl = KThCl5 , 49 ± 3 . ( 1 ) ( 2 ) ( 3 ) ( 4 ) Consider the application of Rules 2 , 3 , and 4 to the above reactions . From the principles of ...
Contents
Appendix Major Literature Sources for High Temperature Chemistry | 36 |
GraphiteGas Reactions | 59 |
Appendix Some Additional Recent Literature on High Temperature GasSolid | 89 |
Copyright | |
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addition alkali metal atoms basic bond dissociation energies Bulewicz calculated Chapter Chem chemical reaction chemical vapor deposition chemistry chloride combustion complex components composition concentration condensed considered corrosion determined diffusion flames discussion dissociation energies effect electron emission enthalpy entropy equilibrium constant example experimental fission fission products fluorides formation free energy fuel gases given H-atom H₂ H₂O halogen heat Hence high temperature species high temperature vapors hydroxide inhibition inhibitor interaction involving ionization ions kcal mol-¹ kinetic mass spectrometric materials metal halide metal oxide mole mole fraction molecular species NaCl nuclear fission observed oxide oxygen Padley partial pressure phase Phys plasma premixed premixed flames present production radical reactants reaction rates reaction zone reactor recent recombination reduced region relatively rocket Section solid solubility spectroscopic stability Sugden surface Symp Table techniques temperature thermal thermodynamic tion vapor deposition vapor species vapor-phase volatile York