High Temperature Vapors: Science and Technology |
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Page 77
... values , i.e. , less than about 10 kcal mol - 1 , to have AS values at the high end of this range . The most probable values of AS and AH for water dimerization are considered to be --- - ASdim - 32 ± 2 cal deg1 mol - 1 and ΔΗ dim ...
... values , i.e. , less than about 10 kcal mol - 1 , to have AS values at the high end of this range . The most probable values of AS and AH for water dimerization are considered to be --- - ASdim - 32 ± 2 cal deg1 mol - 1 and ΔΗ dim ...
Page 144
... values of - AH1 = 40.4 kcal mol - 1 , ΔΗ - AH3 45 kcal mol - 1 , = - ΔΗ = 42 kcal mol - 1 , - AHA = 26 kcal mol - 1 . Clearly these values do not follow the same trend as the experimental data . Consider now the enhanced stabilization ...
... values of - AH1 = 40.4 kcal mol - 1 , ΔΗ - AH3 45 kcal mol - 1 , = - ΔΗ = 42 kcal mol - 1 , - AHA = 26 kcal mol - 1 . Clearly these values do not follow the same trend as the experimental data . Consider now the enhanced stabilization ...
Page 328
... values for elements such as Mg , Mn , Si , and Sr , which form stable oxides or hy- droxides , is thought to be due to the unusually strong dependence of 8 on flame composition , as may be thermodynamically predicted . As an example of ...
... values for elements such as Mg , Mn , Si , and Sr , which form stable oxides or hy- droxides , is thought to be due to the unusually strong dependence of 8 on flame composition , as may be thermodynamically predicted . As an example of ...
Contents
Appendix Major Literature Sources for High Temperature Chemistry | 36 |
GraphiteGas Reactions | 59 |
Appendix Some Additional Recent Literature on High Temperature GasSolid | 89 |
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addition alkali metal atoms basic bond dissociation energies Bulewicz calculated Chapter Chem chemical reaction chemical vapor deposition chemistry chloride combustion complex components composition concentration condensed considered corrosion determined diffusion flames discussion dissociation energies effect electron emission enthalpy entropy equilibrium constant example experimental fission fission products fluorides formation free energy fuel gases given H-atom H₂ H₂O halogen heat Hence high temperature species high temperature vapors hydroxide inhibition inhibitor interaction involving ionization ions kcal mol-¹ kinetic mass spectrometric materials metal halide metal oxide mole mole fraction molecular species NaCl nuclear fission observed oxide oxygen Padley partial pressure phase Phys plasma premixed premixed flames present production radical reactants reaction rates reaction zone reactor recent recombination reduced region relatively rocket Section solid solubility spectroscopic stability Sugden surface Symp Table techniques temperature thermal thermodynamic tion vapor deposition vapor species vapor-phase volatile York