Structural and Magnetic Phase Transitions in MineralsThis volume in Advances in Physical Geochemistry presents the latest synthesis of theory and experimental data pertaining to structural and magnetic phase transitions in a variety of geochemically important minerals. The book is the first to cover the impact of this rapidly progressing area of solid state physics in earth sciences and reflects its growing significance for mineralogy and petrology. |
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Results 1-3 of 47
Page 46
... P , T = Gss dS + Gse ' dɛ ; ds / dɛ ; -GSE GSS Solution calorimetry
experiments provide values for Hmix at constant values for P , T , X , and Y.
Dependence of model estimates of Amix on ε ; includes a contribution from
ordering : dH mix / dɛ ...
... P , T = Gss dS + Gse ' dɛ ; ds / dɛ ; -GSE GSS Solution calorimetry
experiments provide values for Hmix at constant values for P , T , X , and Y.
Dependence of model estimates of Amix on ε ; includes a contribution from
ordering : dH mix / dɛ ...
Page 122
For a state with spin S there are 25 + 1 degenerate microstates . If the orbital
degeneracy is nd , then the total electronic degeneracy , w , is nd ( 2S + 1 ) .
Since Sel = R In ( w ) ( R = gas constant ) , we get ASel = R In Ind ( 25 ! + ) ] – R In
Indk ...
For a state with spin S there are 25 + 1 degenerate microstates . If the orbital
degeneracy is nd , then the total electronic degeneracy , w , is nd ( 2S + 1 ) .
Since Sel = R In ( w ) ( R = gas constant ) , we get ASel = R In Ind ( 25 ! + ) ] – R In
Indk ...
Page 228
8 7.5 DIELECTRIC CONSTANT E 3 PIGIOON 100 6.5 6 270 300 350 400
TEMPERATURE ( K ) 1 MHz . Fig . 7. Temperature dependence of the real part of
the dielectric constant at f Several heating ( 1,3 ) and cooling ( 2,4 ) runs are
shown .
8 7.5 DIELECTRIC CONSTANT E 3 PIGIOON 100 6.5 6 270 300 350 400
TEMPERATURE ( K ) 1 MHz . Fig . 7. Temperature dependence of the real part of
the dielectric constant at f Several heating ( 1,3 ) and cooling ( 2,4 ) runs are
shown .
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Contents
Incommensurate Phase Transitions in Quartz and Berlinite | 17 |
Phase Separation in Quadrilateral Pyroxenes and Olivines | 39 |
Multicritical Phase Relations in Minerals | 60 |
Copyright | |
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Other editions - View all
Structural and Magnetic Phase Transitions in Minerals S. Ghose,J.M.D. Coey,E. Salje Limited preview - 2012 |
Structural and Magnetic Phase Transitions in Minerals S. Ghose,J.M.D. Coey,E. Salje Snippet view - 1988 |
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antiferromagnetic appears applied approximation atoms axis Ballet behavior bond calculated cation Chem chemical cluster Coey components composition constant corresponding coupling critical crystal decreases density dependence described determined diffraction direction disordered Dolino effect electron energy equilibrium estimated et al exchange experimental experiments Fe2+ Fe3+ ferromagnetic field function Ghose give given heat ilvaite inc phase increases indicate interactions ions iron lattice layers lower mantle magnetic magnetic order magnetic structure materials measurements Mineral mode Mössbauer natural neutron observed obtained occur octahedral olivines order parameter pairs perovskite phase diagrams phase transition Phys physical pigeonite polytypes positions possible potential predicted pressure properties pyroxenes quartz range respectively Salje sample shown shows silicates solid solution space group spin stability structure symmetry Table temperature theory thermodynamic tion transformation unit variation