Water and Biological MacromoleculesWesthof Water and Biological Macromolecules presents an excellent description of the structural aspects of water molecules around biological macromolecules. Topics discussed include the properties of water in solid and liquid states; proteins, nucleic acids, polysaccharides, and lipids; and theoretical approaches for understanding the macroscopic observations and integrating microscopic descriptions. The nature and roles of hydration forces in macromolecular complexation and cell-cell interactions are explained, in addition to phenomena such as entropy-enthalpy compensation and the thermodynamic treatment of water bridging. Water and Biological Macromolecules will be a valuable reference for biophysicists, biochemists, and macromolecular biologists. |
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Page 19
... similar to the high - pressure ice structures . 5 Small Crystal Hydrates Several surveys of available small hydrate ... similar . For example , the O · · · O · · · O H - bond angles vary from 70 ° to 150 ° in hydrates , which is similar ...
... similar to the high - pressure ice structures . 5 Small Crystal Hydrates Several surveys of available small hydrate ... similar . For example , the O · · · O · · · O H - bond angles vary from 70 ° to 150 ° in hydrates , which is similar ...
Page 364
... similar order of magnitude ( Gerritsen and Caffrey , 1990 ) but by a factor of nearly 10 lower than the self - diffusion values seen in nuclear magnetic resonance experiments ( Lindblom et al . , 1979 ) . Some of the electrical bilayer ...
... similar order of magnitude ( Gerritsen and Caffrey , 1990 ) but by a factor of nearly 10 lower than the self - diffusion values seen in nuclear magnetic resonance experiments ( Lindblom et al . , 1979 ) . Some of the electrical bilayer ...
Page 367
... similar . The frequency at which the hydrocarbon chains are rotating about their long axes increases with the bound water content , essentially unhindered rotation being achieved at approximately 5 H2O / lipid in the case of phos ...
... similar . The frequency at which the hydrocarbon chains are rotating about their long axes increases with the bound water content , essentially unhindered rotation being achieved at approximately 5 H2O / lipid in the case of phos ...
Contents
Water structure | 3 |
Thermodynamic and dynamic properties of water | 45 |
Aqueous solutions of simple hydrophobic solutes | 55 |
Copyright | |
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Acta Cryst analysis anionic aqueous atoms B-DNA B-form backbone base pairs Beveridge binding Biochemistry Biochim Biol Biomol Biophys Biopolymers calculations Cevc chain Chem Clementi complex conformation counterions crystal structure crystalline crystallographic d(CGCGAATTCGCG density distance dodecamer electron electrostatic Equation experimental Figure force field free energy function Gibbs energy Goodfellow H-bond helix hydration hydration forces hydration shell hydrogen bonds hydrophilic hydrophobic ice Ih interactions interfacial ions lipid bilayers lipid headgroups liquid macromolecules MD simulation membrane minor groove mJ/m² molecular dynamics Molecular dynamics simulation Monte Carlo neutron diffraction nucleic acids nucleotide orientation oxygen phase phosphate groups phosphatidylcholine phospholipid Phys polar polymer polysaccharides potential refinement region relaxation repulsive residues resolution Saenger side-chains solution solvation solvation Gibbs energy solvent solvent molecules solvent structure ẞ-sheet stability Struct studies surface temperature tion water bridges water molecules water structure Westhof X-ray Z-DNA