Surface Chemistry of Surfactants and Polymers

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John Wiley & Sons, Sep 26, 2014 - Science - 496 pages

This book gives the reader an introduction to the field of surfactants in solution as well as polymers in solution. Starting with an introduction to surfactants the book then discusses their environmental and health aspects. Chapter 3 looks at fundamental forces in surface and colloid chemistry. Chapter 4 covers self-assembly and 5 phase diagrams. Chapter 6 reviews advanced self-assembly while chapter 7 looks at complex behaviour. Chapters 8 to 10 cover polymer adsorption at solid surfaces, polymers in solution and surface active polymers, respectively. Chapters 11 and 12 discuss adsorption and surface and interfacial tension, while Chapters 13- 16 deal with mixed surfactant systems. Chapter 17, 18 and 19 address microemulsions, colloidal stability and the rheology of polymer and surfactant solutions. Wetting and wetting agents, hydrophobization and hydrophobizing agents, solid dispersions, surfactant assemblies, foaming, emulsions and emulsifiers and microemulsions for soil and oil removal complete the coverage in chapters 20-25.

 

Contents

Environmental and Health Aspects of Surfactants
49
The Rate of Biodegradation Depends on the Surfactant Structure
55
REACH
62
Two Fundamental Forces in Surface and Colloid Chemistry
65
4
75
5
95
Beyond the Spherical Micelle
113
7
137
36
293
SurfactantProtein Mixtures
295
SurfactantPolymer Mixtures at Interfaces
305
42
308
Microemulsions
315
Colloidal Stability
335
An Introduction to the Rheology of Polymer and Surfactant
361
Wetting and Wetting Agents Hydrophobization
377

Temperature Anomalies of OxyethyleneBased Surfactants and Polymers
150
10
197
Adsorption of Polymers at Solid Surfaces
211
Surface and Interfacial Tension
231
Mixed Surfactant Systems
251
26
267
SurfactantPolymer Systems
271
29
285
Solid Dispersions
391
Surfactant Assemblies as Templates
403
Foaming of Surfactant Solutions
419
Emulsions and Emulsifiers
431
Microemulsions for Soil and Oil Removal
447
Index
467
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About the author (2014)

Krister Holmberg is Professor of Surface Chemistry and Director of Materials Science Area of Advance at Chalmers University of Technology in Göteborg (Sweden). He was awarded a PhD at Chalmers University and after gaining his doctorate, he worked as a researcher at a number of Swedish chemical companies. From 1991 to 1997 he was head of the Surface Chemistry Institute, Stockholm (Sweden). He was also adjunct professor at Göteborg University in Biotechnical Surface Chemistry and at the Royal Institute of Technology in Technical Surface and Colloid Chemistry. Professor Holmberg's current research interests include novel surfactants, organic and bioorganic reactions in organized media such as microemulsions and suspensions of mesoporous materials, and controlled delivery of active substances.

Professor Bengt Kronberg is a Senior Research Fellow and Course Director at SP Technical Research Institute of Sweden. He has a long experience in teaching fundamental and applied aspects of surface chemistry. He has published over 80 papers in the field and is a co-author of the book "Surfactants and Polymers in Aqueous Solution". Professor Kronberg supervises research in the fields of microemulsions, adsorption of surfactants and polymers, fuel formulations, and polymeric networks.

Professor Björn Lindman is senior scientist at the Department of Physical Chemistry, University of Lund, Sweden and Visiting Professor at School of Materials Science & Engineering at Nanyang Technological University, Singapore. He has published more than 600 papers, and co-authored three books and edited more than ten books in the field of surface and colloid chemistry. Furthermore he is a well-known lecturer and consultant worldwide. Professor Lindman's current research projects include: DNA gel particles and cross-linked DNA gels, Controlling the phase behavior of polyion-surfactant ion complex salts by cyclodextrins and associative effects of polyacrylates in surfactant systems.

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