Volatile Partitioning Between Milk Fat and Aqueous Phases as Influenced by Temperature |
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Page 5
Daniel P. Berg. AG = AH - TAS Likewise , these parameters can be considered
under standard state conditions : AG° = AH° - TAS° For dissolution processes ,
the state of equilibrium defines the solubility of the solute in solvent . Under
standard ...
Daniel P. Berg. AG = AH - TAS Likewise , these parameters can be considered
under standard state conditions : AG° = AH° - TAS° For dissolution processes ,
the state of equilibrium defines the solubility of the solute in solvent . Under
standard ...
Page 6
In many cases , unfavorable enthalpy is responsible for immiscibility , as
randomness would generally increase when solvents are mixed . However , the
hydrophobic effect deviates from this expected outcome and warrants further
explanation ...
In many cases , unfavorable enthalpy is responsible for immiscibility , as
randomness would generally increase when solvents are mixed . However , the
hydrophobic effect deviates from this expected outcome and warrants further
explanation ...
Page 10
1 mg . If the analytical procedure has an inherent error of 0 . 05 mg / 100 ml , the
P value could vary between 133 and 400 . If , however , 200 ml of water and 5 ml
of non - polar solvent were used , the water layer would contain 3 . 5 mg or 1 .
1 mg . If the analytical procedure has an inherent error of 0 . 05 mg / 100 ml , the
P value could vary between 133 and 400 . If , however , 200 ml of water and 5 ml
of non - polar solvent were used , the water layer would contain 3 . 5 mg or 1 .
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1-butanol 1-heptanol 1-octanol and water 1-propanol according acetone achieved acid activity Additional alcohols allowed analysis anhydrous milk fat approximately aqueous phase associated calculated cheese chromatography compared comparison compounds concentration conducted constant containing correlation crystal curve decrease dependent determined Deviation difference diffusion dissolved effect emulsion energy enthalpy entropy equilibrium conditions et al ethanol experiments factor fat and water flavor development globule greater groups hydrophobic impact improve increase indicates influenced by temperature initially injection standard interactions less levels limited lipid liquid Log Kmw mass mean measured melting method milk fat minutes mixing models needed observed partition coefficient peak area physical polar prepared properties proteins ratio reactions reduced regression reported sample saturated separate slope solid fat content solubility solute solvent stirring suggest Table understanding values verify versus vial volatiles volume water partitioning