Advanced Organic ChemistryThis survey of advanced chemistry covers virtually all the useful reactions--600 all told--with the scope, limitations, and mechanism of each described in detail. Extensive general sections on the mechanisms of the important reaction types, and five chapters on the structure and stereochemistry of organic compounds and reactive intermediates are included as well. Of the more than 10,000 references included, 5,000 are new in this edition. |
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Page 402
... Grignard reagents . 1020 Grignard reagents have the advantage that they are usually simpler to prepare than the corresponding R2CuLi , but the reaction is much narrower in scope . Grignard reagents couple only with active halides ...
... Grignard reagents . 1020 Grignard reagents have the advantage that they are usually simpler to prepare than the corresponding R2CuLi , but the reaction is much narrower in scope . Grignard reagents couple only with active halides ...
Page 410
... Grignard reagents ( ROAr + R " MgX → RR " + ArOMgX ) . Allylic ethers can be cleaved by Grignard reagents in THF if CuBr is present . 1108 The reaction takes place either with or without allylic rearrangement.1109 Vinylic ethers can ...
... Grignard reagents ( ROAr + R " MgX → RR " + ArOMgX ) . Allylic ethers can be cleaved by Grignard reagents in THF if CuBr is present . 1108 The reaction takes place either with or without allylic rearrangement.1109 Vinylic ethers can ...
Page 559
... Grignard reagent formation ( 7-29 ) , and the reaction is seldom successful with 1,1 - dihalides , though the ... reagents and a - halolithium reagents can be prepared by the method given in 2-38.321 Alkylmagnesium fluorides can be ...
... Grignard reagent formation ( 7-29 ) , and the reaction is seldom successful with 1,1 - dihalides , though the ... reagents and a - halolithium reagents can be prepared by the method given in 2-38.321 Alkylmagnesium fluorides can be ...
Contents
Localized Chemical Bonding | 7 |
Delocalized Chemical Bonding | 25 |
Bonding Weaker than Covalent | 71 |
Copyright | |
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Common terms and phrases
Academic Press acetic Acta acyl addition alcohols aldehydes alkyl halides allylic amines Angew aromatic aryl atom attack base benzene benzylic bromine Bull carbanion carbon carboxylic acids catalyst cation CH₂ Chem Chemistry Chim chiral chloride cleaved compounds conjugated converted cyclopropane diazonium discussion double bond effect electrons electrophilic enantiomers energy Engl enol esters ethers example formed free radicals free-radical give Grignard reagents H₂O halogen hydrogen hydrolysis hydrolyzed intermediate involves isomer ketones leaving group method methyl molecule nitriles nitrogen NO₂ nucleophilic substitution Olah olefins orbitals Organomet organometallic ortho oxygen pair Patai Perkin Trans phenols Phys position prepared primary proton Pure Appl react reaction reactivity rearrangement reduced resonance ring Russ salts secondary SN1 reactions SN2 mechanism solvent stable step steric substrate sulfonic sulfur Synth Synthesis tertiary Tetrahedron Lett treatment triple bonds USSR vinyl Wiley yields York