Advanced Organic ChemistryThis survey of advanced chemistry covers virtually all the useful reactions--600 all told--with the scope, limitations, and mechanism of each described in detail. Extensive general sections on the mechanisms of the important reaction types, and five chapters on the structure and stereochemistry of organic compounds and reactive intermediates are included as well. Of the more than 10,000 references included, 5,000 are new in this edition. |
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Page 37
... ring are related to the presence of a closed loop of electrons , the aromatic sextet ( aromatic compounds are thus the arch examples of delocalized bonding ) , but it still was not easy to determine whether rings other than the benzene ring ...
... ring are related to the presence of a closed loop of electrons , the aromatic sextet ( aromatic compounds are thus the arch examples of delocalized bonding ) , but it still was not easy to determine whether rings other than the benzene ring ...
Page 41
... ring . In naphthalene , if one ring is to have six , the other must have only four . One way to explain the greater reactivity of the ring system of naphthalene compared with benzene is to regard one of the naphthalene rings as aromatic ...
... ring . In naphthalene , if one ring is to have six , the other must have only four . One way to explain the greater reactivity of the ring system of naphthalene compared with benzene is to regard one of the naphthalene rings as aromatic ...
Page 461
... ring B is not ( though the presence of a substituent in a fused ring system affects CH , B A 18 Me H Y 19 HY 20 68 all the rings , the effect is generally greatest on the ring to which it is attached ) . We therefore expect substitution in ...
... ring B is not ( though the presence of a substituent in a fused ring system affects CH , B A 18 Me H Y 19 HY 20 68 all the rings , the effect is generally greatest on the ring to which it is attached ) . We therefore expect substitution in ...
Contents
Localized Chemical Bonding | 7 |
Delocalized Chemical Bonding | 25 |
Bonding Weaker than Covalent | 71 |
Copyright | |
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Common terms and phrases
acetic acid active acyl addition alcohols aldehydes alkyl allylic amines Angew aromatic aryl atom attack base bromine Brown Bull called carbon carboxylic carried catalyst cation Chapter charge Chem Chemistry Chim chloride Commun complex compounds containing converted discussion double bond effect electrons electrophilic energy Engl enol esters ethers evidence example followed formation formed free-radical give halides halogen hydrogen increase intermediate involves ketones known leaving group less mechanism metal method mixture molecule nucleophilic obtained Olah olefins orbitals Organic oxygen pair Perkin Trans Phys position possible prepared presence primary proton radicals reaction reactivity reagents rearrangement reduced resonance ring salts secondary shown side similar solution solvent species stable step structure substitution substrate Synthesis Table take place tertiary Tetrahedron Lett treated treatment usually values Wiley yields York