Fundamentals of Statistical and Thermal Physics, Volume 10This book is devoted to a discussion of some of the basic physical concepts and methods useful in the description of situations involving systems which consist of very many particulars. It attempts, in particular, to introduce the reader to the disciplines of thermodynamics, statistical mechanics, and kinetic theory from a unified and modern point of view. The presentation emphasizes the essential unity of the subject matter and develops physical insight by stressing the microscopic content of the theory. |
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Page 317
... chemical potential per mole . This is given by the relation ( ƏG / dv ; ) ; since v Ni / Na , it is N. times larger than the corresponding chemical = a potential per molecule ( ƏG / ƏN1 ) . One could readily extend the arguments of this ...
... chemical potential per mole . This is given by the relation ( ƏG / dv ; ) ; since v Ni / Na , it is N. times larger than the corresponding chemical = a potential per molecule ( ƏG / ƏN1 ) . One could readily extend the arguments of this ...
Page 320
... chemical potentials , of this mixture of gases . Calculation of the chemical potential We again consider the gases to be at sufficiently high temperature and sufficiently low density that their transla- tional motion can be treated ...
... chemical potentials , of this mixture of gases . Calculation of the chemical potential We again consider the gases to be at sufficiently high temperature and sufficiently low density that their transla- tional motion can be treated ...
Page 363
... chemical potential μπ ( SF ) , = -kT V , T a ln Z ON V , T ( 9.11.1 ) In the last chapter we saw that the chemical potential is the important param- eter determining the equilibrium conditions between phases or chemical com- ponents ...
... chemical potential μπ ( SF ) , = -kT V , T a ln Z ON V , T ( 9.11.1 ) In the last chapter we saw that the chemical potential is the important param- eter determining the equilibrium conditions between phases or chemical com- ponents ...
Contents
Introduction to statistical methods | 1 |
GENERAL DISCUSSION OF THE RANDOM WALK | 24 |
Statistical description of systems of particles | 47 |
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accessible amount approximation assume atoms becomes calculate called classical collision condition Consider consisting constant container corresponding course d³v defined denote depends derivatives described direction discussion distribution electrons energy ensemble entropy equal equation equilibrium evaluated example expression external field final follows force function given gives heat Hence ideal illustrated increase independent integral interaction interest internal involving liquid macroscopic magnetic mass maximum mean measured mechanics method mole molecules momentum Note obtains parameter particles particular partition phase physical position possible pressure probability problem properties quantity quantum quantum mechanics range relation relative remain reservoir respect result satisfy shows simply situation solid specific statistical steps sufficiently Suppose temperature theory thermal Thermodynamics tion unit variables velocity volume write written yields