Fundamentals of Statistical and Thermal Physics, Volume 10This book is devoted to a discussion of some of the basic physical concepts and methods useful in the description of situations involving systems which consist of very many particulars. It attempts, in particular, to introduce the reader to the disciplines of thermodynamics, statistical mechanics, and kinetic theory from a unified and modern point of view. The presentation emphasizes the essential unity of the subject matter and develops physical insight by stressing the microscopic content of the theory. |
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Page 234
... solid . ( b ) Find an expression , as a function of T , of the nuclear contribution to the molar entropy of the solid . ( c ) By directly counting the total number of accessible states , calculate the nuclear contribution to the molar ...
... solid . ( b ) Find an expression , as a function of T , of the nuclear contribution to the molar entropy of the solid . ( c ) By directly counting the total number of accessible states , calculate the nuclear contribution to the molar ...
Page 305
... solid ( s ) to liquid ( 1 ) the entropy of the substance ( or degree of disorder ) almost always increases . † Thus the corresponding latent heat L , is positive and heat gets absorbed in the transformation . In most cases the solid ...
... solid ( s ) to liquid ( 1 ) the entropy of the substance ( or degree of disorder ) almost always increases . † Thus the corresponding latent heat L , is positive and heat gets absorbed in the transformation . In most cases the solid ...
Page 366
... solid . If it consists of N2 atoms and has a volume V2 , its chemical potential is related to its partition function Z by In Z μ2 = ( V. ) T.V . = −kr ( 87 ) -kT 2 T.V2 T.V2 2 ( 9.11.14 ) Although we could try to calculate Z by using a ...
... solid . If it consists of N2 atoms and has a volume V2 , its chemical potential is related to its partition function Z by In Z μ2 = ( V. ) T.V . = −kr ( 87 ) -kT 2 T.V2 T.V2 2 ( 9.11.14 ) Although we could try to calculate Z by using a ...
Contents
Introduction to statistical methods | 1 |
GENERAL DISCUSSION OF THE RANDOM WALK | 24 |
Statistical description of systems of particles | 47 |
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accessible amount approximation assume atoms becomes calculate called classical collision condition Consider consisting constant container corresponding course d³v defined denote depends derivatives described direction discussion distribution electrons energy ensemble entropy equal equation equilibrium evaluated example expression external field final follows force function given gives heat Hence ideal illustrated increase independent integral interaction interest internal involving liquid macroscopic magnetic mass maximum mean measured mechanics method mole molecules momentum Note obtains parameter particles particular partition phase physical position possible pressure probability problem properties quantity quantum quantum mechanics range relation relative remain reservoir respect result satisfy shows simply situation solid specific statistical steps sufficiently Suppose temperature theory thermal Thermodynamics tion unit variables velocity volume write written yields