## Treatise on Materials Science and Technology, Volume 4 |

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Page 79

It

description of experiments . It is likely that this causes much misinterpretation in

the results of experimental work . Nevertheless , these models do give a great

deal ...

It

**becomes**difficult to tell where a complex model**becomes**inadequate in thedescription of experiments . It is likely that this causes much misinterpretation in

the results of experimental work . Nevertheless , these models do give a great

deal ...

Page 200

( 65 ) In - = - RT o ) - X 0 , 0 RT Since G is a function of H and S , let us now

evaluate the enthalpy and entropy terms separately . From Eqs . ( 18 ) , ( 27 ) ,

and ( 32 ) , the expression for the enthalpy term

4zx + 1 ...

( 65 ) In - = - RT o ) - X 0 , 0 RT Since G is a function of H and S , let us now

evaluate the enthalpy and entropy terms separately . From Eqs . ( 18 ) , ( 27 ) ,

and ( 32 ) , the expression for the enthalpy term

**becomes**( 66 ) H = { RTB ( 4z2 +4zx + 1 ...

Page 206

From Eqs . ( 51 ) and ( 66 ) , the difference between the enthalpy of the alloy at

any composition x and that at stoichiometry

+ x2 ) 1 / 2 ] – { ZNx ( Haa – HBB ) ( 87 ) According to this relationship , H is an ...

From Eqs . ( 51 ) and ( 66 ) , the difference between the enthalpy of the alloy at

any composition x and that at stoichiometry

**becomes**H – H , = { RTB [ 2a – ( 4a2+ x2 ) 1 / 2 ] – { ZNx ( Haa – HBB ) ( 87 ) According to this relationship , H is an ...

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### Contents

RICHARD W VOOK | 2 |

Epitaxial Monocrystalline Films | 10 |

Polycrystalline Films | 37 |

Copyright | |

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activity addition alloys applied approximation average beam becomes calculated compaction component composition compression concentration considered constant copper correlation corresponding crystal cubic curve decreases defined deformation density dependence determined diffraction diffusion direction discussed dislocation disorder distribution effect electron elements energy enthalpy entropy equations example experimental expression factor fault field Figure forged function given gives increases influence interaction jump lattice material measurements mechanism metal method neighbor observed obtained occurs oriented parameter partial pattern phases Phys plane polycrystalline position possible powder present probability production properties random ratio reflections region relative respectively shown in Fig shows single crystals sintered solid solution solute atoms solvent strain strengthening stress structure Substituting surface Table temperature theoretical theory thermodynamic thin films tracer twin vacancy values variations volume X-ray yield