## Treatise on Materials Science and Technology, Volume 4 |

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Page 183

Accordingly , we have only one way of distributing the two kinds of atoms on the

sublattices , W = 1 . The corresponding configurational

Boltzmann equation ( Eq . ( 7 ) ] is zero . At nonstoichiometric compositions , i . e .

Accordingly , we have only one way of distributing the two kinds of atoms on the

sublattices , W = 1 . The corresponding configurational

**entropy**S , according toBoltzmann equation ( Eq . ( 7 ) ] is zero . At nonstoichiometric compositions , i . e .

Page 210

002 PARTIAL FREE ENERGY , ENTHALPY AND

OC = 0 . 020 ( 52 - 520 / R , OC = 0 . 002 in Oz / Ozp , OC = 0 . 020 7 20C ( 52 -

320 ) / R , OC = 0 . 020 OLUN 0 0 . 01 0 . 02 IIIIIIIII 0 . 03 0 . 04 0 . 05 0 . 06 0 . 07

0 .

002 PARTIAL FREE ENERGY , ENTHALPY AND

**ENTROPY**( A2 - A2 , 0 ) / RT ,OC = 0 . 020 ( 52 - 520 / R , OC = 0 . 002 in Oz / Ozp , OC = 0 . 020 7 20C ( 52 -

320 ) / R , OC = 0 . 020 OLUN 0 0 . 01 0 . 02 IIIIIIIII 0 . 03 0 . 04 0 . 05 0 . 06 0 . 07

0 .

Page 223

Since the enthalpy expression is different from that for the CsCl phases , the

theoretical equations to be presented below for thermodynamic activity and

partial enthalpy will be different but the expressions for the partial

the same ...

Since the enthalpy expression is different from that for the CsCl phases , the

theoretical equations to be presented below for thermodynamic activity and

partial enthalpy will be different but the expressions for the partial

**entropy**will bethe same ...

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### Contents

RICHARD W VOOK | 2 |

Epitaxial Monocrystalline Films | 10 |

Polycrystalline Films | 37 |

Copyright | |

2 other sections not shown

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### Common terms and phrases

activity addition alloys applied approximation average beam becomes calculated compaction component composition compression concentration considered constant copper correlation corresponding crystal cubic curve decreases defined deformation density dependence determined diffraction diffusion direction discussed dislocation disorder distribution effect electron elements energy enthalpy entropy equations example experimental expression factor fault field Figure forged function given gives increases influence interaction jump lattice material measurements mechanism metal method neighbor observed obtained occurs oriented parameter partial pattern phases Phys plane polycrystalline position possible powder present probability production properties random ratio reflections region relative respectively shown in Fig shows single crystals sintered solid solution solute atoms solvent strain strengthening stress structure Substituting surface Table temperature theoretical theory thermodynamic thin films tracer twin vacancy values variations volume X-ray yield