## Treatise on materials science and technology, Volume 4 |

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Page 199

B.

experimental data, it is essential to derive equations based on this model which

can ...

B.

**Thermodynamic**Properties (Activity, Partial Enthalpy, and Partial Entropy) 1.**Thermodynamic**Activity Since any theoretical model must be substantiated byexperimental data, it is essential to derive equations based on this model which

can ...

Page 205

strongly recommended that the equation derived based on the one-and-half

approximation be used in describing the compositional dependences of the

atoms, ...

strongly recommended that the equation derived based on the one-and-half

approximation be used in describing the compositional dependences of the

**thermodynamic**activities. Since the two sublattices contain an equal number ofatoms, ...

Page 223

We will now proceed to derive theoretical equations for all three

properties following those of Gyuk et al. (1973). Since the enthalpy expression is

different from that for the CsCl phases, the theoretical equations to be presented

...

We will now proceed to derive theoretical equations for all three

**thermodynamic**properties following those of Gyuk et al. (1973). Since the enthalpy expression is

different from that for the CsCl phases, the theoretical equations to be presented

...

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### Contents

Microstructural Characterization of Thin Films | 2 |

Fundamental Concepts of Diffraction | 4 |

Epitaxial Monocrystalline Films | 10 |

Copyright | |

26 other sections not shown

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### Common terms and phrases

a-sublattice Acta alloys aluminum average beam calculated compaction component compositional dependences compression concentration configurational entropy copper correlation factor crystallites CsCl phases decreases deformation diffraction pattern diffusion coefficient dislocation density disorder parameter effect electron diffraction equations Evans and Flanagan f.c. tetragonal face-centered cubic fiber axis flux forged free energy function Gibbs free energy given increases intermetallic iron powder isostatic jump rate lattice disorder material matrix mechanism nearest neighbor observed obtained occurs oriented partial enthalpy partial entropy Phys plane Poisson ratio polycrystalline probability pure metals random reciprocal lattice relps RHEED shear stress shown in Fig single crystals sintered sintered powder solid solution strengthening solute atoms solute content specimen stacking fault energy stoichiometry stress-strain curve structure sublattice Substituting surface Suzuki TED pattern temperature dependence tetragonal theoretical thermal thermodynamic thermodynamic activities thermodynamic properties thin films tracer jump twin vacancy jumps values variations Vook X-ray yield stress