Advanced Organic Chemistry: Reactions and synthesis

acetic acylation adduct alcohols aldehydes aldol alkenes alkenyl alkyl alkynes allylic amides amines anion anti aromatic aryl borane boron bromide C=C H C₂H carbanions carbonyl carbonyl compounds carbonyl group carboxylic acids catalysts CH,O CH₂ CH₂OH CH3 CH CHAPTER 6 CYCLOADDITIONS Chem CO,CH CO₂C₂H CO₂H cyclic cycloaddition reactions derivatives Diels-Alder diene dienophile double bond E. J. Corey electron ENAMINES enantioselectivity enol ethers esters examples formation formed FUNCTIONAL GROUPS give Grignard reagents H C=C H CH H H H H,C CH H,C H,C H. C. Brown H₁C H₂C H₂O halides halogen hydride hydroboration hydrogen intermediate intramolecular ketones Lewis acid lithium mechanism methyl molecules n-BuLi NUCLEOPHILIC SUBSTITUTION orbital organoboranes organolithium organometallic oxidation Ph Ph PhCH₂O prepared proton radical react reaction conditions REACTIONS INVOLVING reactive ring Scheme SECTION sodium solvents stereochemistry stereoselectivity steric structure Synth synthetic Tetrahedron Lett THERMAL ELIMINATIONS TRANSITION METALS UNIMOLECULAR REARRANGEMENTS ylides