Advanced Organic Chemistry: Reactions and synthesisPlenum Press, 1990 - Chemistry, Organic |
Contents
Alkylation of Nucleophilic Carbon Enolates and Enamines | 1 |
CONTENTS | 3 |
Polar Addition and Elimination Reactions | 6 |
Copyright | |
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acylation adduct alcohols aldehydes aldol condensations alkenes ALKYLATION OF NUCLEOPHILIC allylic amides amines anion anti boron bromide C₂H carbanions CARBON NUCLEOPHILES carbon-carbon carbonyl compounds CARBONYL GROUPS carboxylic acids catalyst cation CH,O CH₂ CH₂OH CH3 CH3 CHAPTER 1 ALKYLATION CHAPTER 2 REACTIONS Chem chloride Claisen rearrangement CO,CH CO₂C₂H CO₂H conjugate addition cyclic cycloaddition reactions deprotonation Diels-Alder dienophile DMSO double bond E. J. Corey ELECTROPHILIC ADDITIONS ENAMINES enantioselective ENOLATES AND ENAMINES entry esters examples formation FUNCTIONAL GROUPS give H CH H H H H,C CH H,C H,C H. C. Brown H₂C H₂O halogen hydride hydrogen imine intermediate intramolecular ketones lithium mechanism metal methyl molecules NUCLEOPHILES WITH CARBONYL NUCLEOPHILIC CARBON NUCLEOPHILIC SUBSTITUTION organoboranes oxidation oxygen PhCH₂O proton react reaction conditions REACTIONS OF CARBON reactive reagents regioselectivity Scheme SECTION sodium solvents stereochemistry stereoselectivity steric structure Synth synthesis synthetic Tetrahedron Lett THERMAL ELIMINATIONS transition ylides