Physical Properties of Polymers

aqueous phase calculated chain transfer charge Chem Chem Phys chemical potential conformation copolymer correlation counterions curves decrease density dependence derived desorption diffusion coefficient dm³ dynamic effect emulsifier emulsifier concentration emulsion polymerization equation equilibrium excluded volume experimental flexible polyions Flory PJ flow formation free energy function growing radicals Hadjichristidis increases with increasing intermolecular ionic strength kinetic latex particles light scattering low ionic strength Macromolecules Makromol Chem mol dm-3 molar mass molecular weight monomer monomer concentration monomer droplets non-equilibrium number of particles observed obtained parameter peroxodisulfate persistence length poly(vinyl chloride polyelectrolyte polyelectrolyte solutions polyion concentration Polym Sci polymer particles polymer solutions polymeriz polymerization of VC polymerization of vinyl primary radical propagation rate constant rate of polymerization reaction order regime salt concentration scattered intensity Sect shear rate solubility solvent structure factor temperature tensor termination thermodynamic tion vinyl chloride viscosity worm-like chain