New Trends in Physics and Physical Chemistry of Polymers

Front Cover
Springer Science & Business Media, Dec 6, 2012 - Science - 662 pages
Between June 6-10, 1988, the Third Chemical Congress of North America was held at the Toronto Convention Center. At this rare gathering, fifteen thousand scientists attended various symposia. In one of the symposia, Professor Pierre-Gilles de Gennes of College de France was honored as the 1988 recipient of the Amer ican Chemical Society Polymer Chemistry Award, sponsored by Mobil Chemical Corporation. For Professor de Gennes, this international setting could not be more fitting. For years, he has been a friend and a lecturer to the world scientific community. Thus, for this special occasion, his friends came to recount many of his achievements or report new research findings mostly derived from his theories or stimulated by his thoughts. In this volume of Proceedings, titled New Trends in Physics and Physical Chemistry of Polymers, we are glad to present the revised papers for the Symposium and some contributed after the Symposium. In addition, we intend to include most of the lively discussions that took plaGe during the conference. This volume contains a total of thirty-six papers divided into six parts, primarily according to the nature of the subject matter: • Adsorption of Colloids and Polymers. • Adhesion, Fractal and Wetting of Polymers. • Dynamics and Characterization of Polymer Solutions. • Diffusion and Interdiffusion of Polymers. • Entanglement and Reptation of Polymer Melts and Networks. • Phase Transitions and Gel Electrophoresis.
 

Contents

PierreGilles De Gennes 1988 Recipient of the ACS Award in Polymer
6
Equilibrium Structure of the Fluid Interface
19
Displacement of Homopolymer From a Surface by a Block Copolymer
41
The Modification of Surface Forces by Grafted Polymer Chains
47
Persistence Length in Microemulsion Systems
57
The Interfacial
63
Chiral Discrimination in Monolayer Packing of Hexadecanol
81
Discussion
89
Discussion
307
Diffusion in Block Copolymers and Isotopic Polymer Mixtures
319
Polystyrene
345
Selfdiffusion of Polydimethylsiloxane Chains
355
Chain Segment Ordering in Strained Rubbers
367
Viscoelasticity and Selfdiffusion in Miscible Heteropolymer Blends
375
Discussion
385
Reptation
397

New Perspectives on Polymer Adhesion Mechanisms
95
Dynamics and Fractal Structure of Polymer Interfaces
129
Size Exclusion Chromatography and Surface Effects in Porous Fractals
137
Role of Long
159
Wetting Phenomena
171
Applications of HardSoft AcidBase HSAB Principle to Solid
185
Discussion
201
PolymerPolymerGood Solvent
229
Excimer Studies of Polymer Solutions Over the Entire Concentration
239
A Study by Neutron Reflection
255
Theory of Dynamic Screening in Macromolecular Solutions
269
Tracer Diffusion in Polymerlike Networks
285
Dynamical Properties of Semidilute Polymer Solutions at the Theta
293
The Entanglement Concept in Polymer Physics Revisited
419
Repton Model of Entangled Polymers
455
On the Effect of Positional Order on the Scattering
471
Calculation of Elastic SmallAngle Neutron Scattering from Labeled
483
Discussion
497
Percolation Type Growth Process of Clusters Near the Gelation
531
The Biased Reptation Model of DNA Gel Electrophoresis
547
FINAL REMARKS
601
ABOUT THE CONTRIBUTORS
625
AUTHOR INDEX
631
SUBJECT INDEX
643
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