Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications ... |
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Page 185
... expression for the full equilibrium constant is incorporated in the con- ventional basic dissociation constant K. If the base is the only solute present , then [ OH- ] = [ conjugate acid ] and the approximate equation for a small degree ...
... expression for the full equilibrium constant is incorporated in the con- ventional basic dissociation constant K. If the base is the only solute present , then [ OH- ] = [ conjugate acid ] and the approximate equation for a small degree ...
Page 363
... expressing the reaction rate as a function of factors that are thermodynamic , or at least pseudo- thermodynamic ... expression for the rate constant : ᎡᎢ k = -e - AG ° ‡ / RT Nh ( 10-108 ) Next we divide the free energy of ...
... expressing the reaction rate as a function of factors that are thermodynamic , or at least pseudo- thermodynamic ... expression for the rate constant : ᎡᎢ k = -e - AG ° ‡ / RT Nh ( 10-108 ) Next we divide the free energy of ...
Page 386
... expression of the form of Equation ( 10-183 ) . Indeed , no matter how many sequential intermediates there are in ... expressions than in the single - intermediate case , and there are not enough of these measurable parameters to permit ...
... expression of the form of Equation ( 10-183 ) . Indeed , no matter how many sequential intermediates there are in ... expressions than in the single - intermediate case , and there are not enough of these measurable parameters to permit ...
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absorption acid activity adsorbed adsorption amino amount behavior benzene Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride cm³ coefficient complex components concentration containing corresponding curve described diagram dipole dissociation distance effect electric electrolyte electron enthalpy entropy enzyme equal equation equilibrium constant example force free energy frequency function H₂O heat hydrogen atom hydrogen bonds increase interaction ionic ionization k₂ kcal kinetic magnetic field magnitude material measured membrane mixture molar mole fraction molecular weight molecules nuclei occurs orbital osmotic pressure oxidation oxygen particles polar potential protein proton quantum number radiation rate constant ratio reactant reaction represented resonance rotation sample shown in Figure sodium solid solubility solvent species spectra spectrum spin structure substance substrate sucrose surface tension temperature tion titration torr transition triplet tube vapor pressure velocity vibrational viscosity volume wave wavelength zero