Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications ... |
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Page 358
... constants for two temperatures 10 K apart is often referred to as the Q10 of a reaction . For complex reactions , as we have seen , the measured rate constant may well be a composite with factors from several elementary process rate ...
... constants for two temperatures 10 K apart is often referred to as the Q10 of a reaction . For complex reactions , as we have seen , the measured rate constant may well be a composite with factors from several elementary process rate ...
Page 367
... equilibrium constant for a revers- ible reaction and the rate constants for the forward and reverse reac- tions . For the equilibrium system A + B + C + D k_ ( 10-115 ) the true equilibrium constant is given by an equation involving the ...
... equilibrium constant for a revers- ible reaction and the rate constants for the forward and reverse reac- tions . For the equilibrium system A + B + C + D k_ ( 10-115 ) the true equilibrium constant is given by an equation involving the ...
Page 393
... rate equation dx = k1 ( x + [ A ]。) − k_1 ( [ C ]。− x ) ( 10-199 ) dt However , the equilibrium concentrations are related by k1 [ A ] = k_1 [ C ] . ( 10-200 ) Therefore dx dt = ( k1 + ... rate constant of 10-11 VERY RAPID REACTIONS 393.
... rate equation dx = k1 ( x + [ A ]。) − k_1 ( [ C ]。− x ) ( 10-199 ) dt However , the equilibrium concentrations are related by k1 [ A ] = k_1 [ C ] . ( 10-200 ) Therefore dx dt = ( k1 + ... rate constant of 10-11 VERY RAPID REACTIONS 393.
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absorption acid activity adsorbed adsorption amino amount behavior benzene Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride cm³ coefficient complex components concentration containing corresponding curve described diagram dipole dissociation distance effect electric electrolyte electron enthalpy entropy enzyme equal equation equilibrium constant example force free energy frequency function H₂O heat hydrogen atom hydrogen bonds increase interaction ionic ionization k₂ kcal kinetic magnetic field magnitude material measured membrane mixture molar mole fraction molecular weight molecules nuclei occurs orbital osmotic pressure oxidation oxygen particles polar potential protein proton quantum number radiation rate constant ratio reactant reaction represented resonance rotation sample shown in Figure sodium solid solubility solvent species spectra spectrum spin structure substance substrate sucrose surface tension temperature tion titration torr transition triplet tube vapor pressure velocity vibrational viscosity volume wave wavelength zero