Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications ... |
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Page 351
... step is rapid and reversible and the second step is rate- determining , so that k2 is small compared to both k1 and k_ ,, the rate of the reaction is equal to the rate of the second step : rate = k2 [ N2O2 ] [ Cl2 ] 1 ( 10-47 ) However ...
... step is rapid and reversible and the second step is rate- determining , so that k2 is small compared to both k1 and k_ ,, the rate of the reaction is equal to the rate of the second step : rate = k2 [ N2O2 ] [ Cl2 ] 1 ( 10-47 ) However ...
Page 353
... Step 3 ( 10-53 ) The chain is continued as this bromine atom reacts with a hydrogen molecule , in step 2. Step 2 and step 3 are both propagation steps , be- cause they contribute to the route to the product but do not diminish the ...
... Step 3 ( 10-53 ) The chain is continued as this bromine atom reacts with a hydrogen molecule , in step 2. Step 2 and step 3 are both propagation steps , be- cause they contribute to the route to the product but do not diminish the ...
Page 372
... step may be the transfer of a proton from the catalyst , HA , to the glucose molecule , which we shall here represent as HG : HA + HG HGH ++ A- ` k_1 ( 10-136 ) This is assumed to be a reversible process and one in which equilibrium is ...
... step may be the transfer of a proton from the catalyst , HA , to the glucose molecule , which we shall here represent as HG : HA + HG HGH ++ A- ` k_1 ( 10-136 ) This is assumed to be a reversible process and one in which equilibrium is ...
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absorption acid activity adsorbed adsorption amino amount behavior benzene Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride cm³ coefficient complex components concentration containing corresponding curve described diagram dipole dissociation distance effect electric electrolyte electron enthalpy entropy enzyme equal equation equilibrium constant example force free energy frequency function H₂O heat hydrogen atom hydrogen bonds increase interaction ionic ionization k₂ kcal kinetic magnetic field magnitude material measured membrane mixture molar mole fraction molecular weight molecules nuclei occurs orbital osmotic pressure oxidation oxygen particles polar potential protein proton quantum number radiation rate constant ratio reactant reaction represented resonance rotation sample shown in Figure sodium solid solubility solvent species spectra spectrum spin structure substance substrate sucrose surface tension temperature tion titration torr transition triplet tube vapor pressure velocity vibrational viscosity volume wave wavelength zero