Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications ... |
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Page 313
... vibrational differences , which are in turn enlarged compared to the electronic energy difference . from this regularity . One cause is centrifugal distortion : As the mole- cule rotates ... VIBRATIONAL SPECTRA 313 9-8 Vibrational Spectra.
... vibrational differences , which are in turn enlarged compared to the electronic energy difference . from this regularity . One cause is centrifugal distortion : As the mole- cule rotates ... VIBRATIONAL SPECTRA 313 9-8 Vibrational Spectra.
Page 539
... vibrational level of the ground state . The b1 and b , arrows represent possible excitations from the first excited vibrational level of the ground state . Transition b1 leads directly to molecular dissociation . ELECTRONIC EXCITATION ...
... vibrational level of the ground state . The b1 and b , arrows represent possible excitations from the first excited vibrational level of the ground state . Transition b1 leads directly to molecular dissociation . ELECTRONIC EXCITATION ...
Page 551
... vibrational modes . 100 020 CO2 levels ergies of these levels are almost the same as those of the asymmetric stretching vibration of CO2 , and energy transfer to this vibrational mode of CO2 occurs by collisions , populating the level ...
... vibrational modes . 100 020 CO2 levels ergies of these levels are almost the same as those of the asymmetric stretching vibration of CO2 , and energy transfer to this vibrational mode of CO2 occurs by collisions , populating the level ...
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absorption acid activity adsorbed adsorption amino amount behavior benzene Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride cm³ coefficient complex components concentration containing corresponding curve described diagram dipole dissociation distance effect electric electrolyte electron enthalpy entropy enzyme equal equation equilibrium constant example force free energy frequency function H₂O heat hydrogen atom hydrogen bonds increase interaction ionic ionization k₂ kcal kinetic magnetic field magnitude material measured membrane mixture molar mole fraction molecular weight molecules nuclei occurs orbital osmotic pressure oxidation oxygen particles polar potential protein proton quantum number radiation rate constant ratio reactant reaction represented resonance rotation sample shown in Figure sodium solid solubility solvent species spectra spectrum spin structure substance substrate sucrose surface tension temperature tion titration torr transition triplet tube vapor pressure velocity vibrational viscosity volume wave wavelength zero