Polymer Interface and AdhesionPoly mer Interface and Adhesion provides the critical basis for further advancement in thisfield. Combining the principles of interfacial science, rheology, stress analysis, and fracturemechanics, the book teaches a new approach to the analysis of long standing problemssuch as: how is the interface formed; what are its physical and mechanical properties;and how does the interface modify the stress field and fracture strength of the material.The book offers many outstanding features, including extensive listings of pertinent references,exhaustive tabulations of the interfacial properties of polymers, critical reviews ofthe many conflicting theories, and complete discussions of coupling agents, adhesion promotion,and surface modifications. Emphasis is placed on physical concepts and mechanisms,using clear, understandable mathematics.Polymer Interface and Adhesion promotes a more thorough understanding of the physical,mechanical, and adhesive properties of multiphase, polymer systems. Polymer scientistsand engineers, surface chemists, materials scientists, rheologists, as well as chemical andmechanical engineers interested in the research, development or industrial applications ofpolymers, plastics, fibers, coatings, adhesives, and composites need this important newsource book. |
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Results 1-5 of 52
Page 15
... maximum advancing contact angle. Removal of the liquid will make the drop become flatter without moving its periphery, and the contact angle will become smaller. When enough liquid is removed, the drop front will suddenly retract. The ...
... maximum advancing contact angle. Removal of the liquid will make the drop become flatter without moving its periphery, and the contact angle will become smaller. When enough liquid is removed, the drop front will suddenly retract. The ...
Page 16
... maximum advancing angle and the minimum receding angle, respectively. On the other hand, if there is no hysteresis, the drop will roll down at the slightest tilt of the plate. This shows that contact angle hysteresis arises from the ...
... maximum advancing angle and the minimum receding angle, respectively. On the other hand, if there is no hysteresis, the drop will roll down at the slightest tilt of the plate. This shows that contact angle hysteresis arises from the ...
Page 18
... maximum and the minimum macroscopic angles are 0. V. a max (1.57) 0 max a max (1.58) min . = 0 0 — where amax is the maximum inclination of the surface. The second is that not all values of 0 are allowed. There are only two positions for ...
... maximum and the minimum macroscopic angles are 0. V. a max (1.57) 0 max a max (1.58) min . = 0 0 — where amax is the maximum inclination of the surface. The second is that not all values of 0 are allowed. There are only two positions for ...
Page 19
... maximum advancing and the minimum receding angle. The energy barriers increase with increasing ridge height and ridge slope [33]. Observed macroscopic angles will therefore depend on the mechanical (vibrational) energy of the drop. For ...
... maximum advancing and the minimum receding angle. The energy barriers increase with increasing ridge height and ridge slope [33]. Observed macroscopic angles will therefore depend on the mechanical (vibrational) energy of the drop. For ...
Page 23
... maximum near Qq and approach zero at 001 and e02- The observed macroscopic angles will, again, depend on the vibrational energy of the liquid drop, e. Hysteresis curves can be constructed using e as for rough surfaces. A family of ...
... maximum near Qq and approach zero at 001 and e02- The observed macroscopic angles will, again, depend on the vibrational energy of the liquid drop, e. Hysteresis curves can be constructed using e as for rough surfaces. A family of ...
Contents
1 | |
29 | |
3 INTERFACIAL AND SURFACE TENSIONS OF POLYMER MELTS AND LIQUIDS | 67 |
4 CONTACT ANGLES OF LIQUIDS ON SOLID POLYMERS | 133 |
5 SURFACE TENSION AND POLARITY OF SOLID POLYMERS | 169 |
6 WETTING OF HIGHENERGY SURFACES | 215 |
7 DYNAMIC CONTACT ANGLES AND WETTING KINETICS | 235 |
8 EXPERIMENTAL METHODS FOR CONTACT ANGLES AND INTERFACIAL TENSIONS | 257 |
11 FORMATION OF ADHESIVE BOND | 359 |
12 WEAK BOUNDARY LAYERS | 449 |
13 EFFECT OF INTERNAL STRESS ON BOND STRENGTH | 465 |
14 FRACTURE OF ADHESIVE BOND | 475 |
15 CREEP FATIGUE AND ENVIRONMENTAL EFFECTS | 571 |
Calculation of Surface Tension and Its Nonpolar and Polar Components from Contact Angles by the HarmonicMean and the GeometricMean Methods | 613 |
Unit Conversion Tables | 619 |
Index | 621 |
MECHANISMS OF WETTABILITY AND BONDABILITY IMPROVEMENTS | 279 |
BASIC CONCEPT AND LOCUS OF FAILURE | 337 |
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Common terms and phrases
acid adherend adhesive adhesive bond aluminum analysis Appl applied attraction bond bond strength bondability boundary layer bulk calculated Chem chemical cohesive Colloid Interface Sci constant contact angle crack critical cross-linked curve decrease density depends diffusion discussed drop dyne/cm Effect equation equilibrium ethylene experimental failure Figure force formed fracture energy function given gives glass groups hand increases interaction interfacial interfacial tension joint layer liquid loading lower materials maximum measured mechanical melt metal methacrylate method mode molecular molecules obtained occurs oxide peel phase Phys plasma plastic plate plot polar Poly Poly vinyl polyethylene Polym polystyrene predicted Press pressure region relation rubber separation shear shown shows silane solid solution specimen spreading strength stress surface tension Table temperature tensile term theory thickness tion treated treatment unit values various versus volume weight wettability wetting York zero