Block Copolymers: Overview and Critical SurveyBlock Copolymers: Overview and Critical Survey is a critical review of block copolymer technology and a comprehensive critical survey on the synthesis, characterization, properties, and applications of the specific block copolymer structures reported in the literature. The copolymers are organized according to segmental architecture and chemical composition. Comprised of seven chapters, this book begins with an overview of what block copolymers are, how they are made, and what they can and cannot be expected to do. The next chapter defines block copolymers and compares them with other types of polymer "hybrids," that is, polymer blends, random copolymers, and graft copolymers. The various segmental architectures that are possible with block copolymers are then described, followed by a discussion on the various synthesis techniques applicable to block copolymers; the characterization methods capable of elucidating block copolymer structures; some applications of commercially available block copolymers; and some future challenges for block copolymer technology. The last three chapters are devoted to A-B diblock copolymers, A-B-A triblock copolymers, and (A-B)n multiblock copolymers. This monograph should be useful to readers who want to become generally conversant with block copolymer technology and to those who need to delve more deeply into the subject. |
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Page 22
... Block and Graft Copolymers . " Butterworth , London , 1962 . D4 . Fischer ... Blocks ” ( L. H. Sperling , ed . ) , p . 157. Plenum , New York , 1974 . D6 ... A. B. , Woods , D. K. , and Stannett , V. , J. Polym . Sci . , Part A - 1 6 ...
... Block and Graft Copolymers . " Butterworth , London , 1962 . D4 . Fischer ... Blocks ” ( L. H. Sperling , ed . ) , p . 157. Plenum , New York , 1974 . D6 ... A. B. , Woods , D. K. , and Stannett , V. , J. Polym . Sci . , Part A - 1 6 ...
Page 24
... blocks . Another , but less common , variation is the radial block copolymer . This structure takes the form of a star - shaped macromolecule in which www A BLOCKS A - B ARCHITECTURE mm B BLOCKS 24 Chapter 3. Block Copolymer Architecture.
... blocks . Another , but less common , variation is the radial block copolymer . This structure takes the form of a star - shaped macromolecule in which www A BLOCKS A - B ARCHITECTURE mm B BLOCKS 24 Chapter 3. Block Copolymer Architecture.
Page 25
... A - B ARCHITECTURE mm B BLOCKS A DOMAINS B.BLOCKS A BLOCKS mmx my min A - B - A ARCHITECTURE A BLOCKS A DOMAINS B BLOCKS Jon ( A - B ARCHITECTURE Fig . 3-1 . Schematic representation of various block copolymer architectures . three or ...
... A - B ARCHITECTURE mm B BLOCKS A DOMAINS B.BLOCKS A BLOCKS mmx my min A - B - A ARCHITECTURE A BLOCKS A DOMAINS B BLOCKS Jon ( A - B ARCHITECTURE Fig . 3-1 . Schematic representation of various block copolymer architectures . three or ...
Page 26
Overview and Critical Survey Allen Noshay, James E. McGrath. ши A BLOCKS B BLOCKS 3- POINT RADIAL 6- POINT RADIAL Fig . 3-2 . Radial block copolymer subarchitectures . ( A - B ) n . Detailed information and references to the original ...
Overview and Critical Survey Allen Noshay, James E. McGrath. ши A BLOCKS B BLOCKS 3- POINT RADIAL 6- POINT RADIAL Fig . 3-2 . Radial block copolymer subarchitectures . ( A - B ) n . Detailed information and references to the original ...
Page 27
... A - B - A and ( A - B ) n block copolymers is responsible for the development of an entire new technology — thermoplastic elastomers . Block copolymers of this type are characterized by a combination of features that were previously ...
... A - B - A and ( A - B ) n block copolymers is responsible for the development of an entire new technology — thermoplastic elastomers . Block copolymers of this type are characterized by a combination of features that were previously ...
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Common terms and phrases
A-B block A-B-A block copolymers a-methylstyrene adipate anionic behavior bisphenol blends Block and Graft block copolymer structures block copolymers block copolymers containing British Patent butadiene catalyst CH₂ Chapter Chem Chemical compositions copoly copolymerization cross-linked crystalline diisocyanate Dimethylsiloxane diol display domains elastomeric end groups ethylene oxide films French Patent German Offen graft copolymers homopolymers initiation Internationale Research Maatschappij isoprene Japanese Patent Macromolecules Makromol Matzner mechanical properties melting point methacrylate methyl modulus molecular weight monomer morphology Netherlands Patent Appl Noshay oligomers phase Phillips Petroleum Phillips Petroleum Co phosgenation Plast poly(ethylene oxide polyamide polybutadiene polycaprolactone polyester polyether Polym polymerization polypropylene polystyrene polysulfone polyurethanes prepared random copolymers reaction reported Research Maatschappij N.V. Rubber Scheme segments Shell Internationale Research siloxane Soedin solubility solution solvent styrene styrene-butadiene styrene-butadiene-styrene synthesis techniques temperature terephthalate Tetramethylene thermal tion two-phase U.S. Patent urethane viscosity Vysokomol