Block Copolymers: Overview and Critical SurveyBlock Copolymers: Overview and Critical Survey is a critical review of block copolymer technology and a comprehensive critical survey on the synthesis, characterization, properties, and applications of the specific block copolymer structures reported in the literature. The copolymers are organized according to segmental architecture and chemical composition. Comprised of seven chapters, this book begins with an overview of what block copolymers are, how they are made, and what they can and cannot be expected to do. The next chapter defines block copolymers and compares them with other types of polymer "hybrids," that is, polymer blends, random copolymers, and graft copolymers. The various segmental architectures that are possible with block copolymers are then described, followed by a discussion on the various synthesis techniques applicable to block copolymers; the characterization methods capable of elucidating block copolymer structures; some applications of commercially available block copolymers; and some future challenges for block copolymer technology. The last three chapters are devoted to A-B diblock copolymers, A-B-A triblock copolymers, and (A-B)n multiblock copolymers. This monograph should be useful to readers who want to become generally conversant with block copolymer technology and to those who need to delve more deeply into the subject. |
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Page xiii
... Bisphenol A Carbonate 416 b . Tetramethyl - 1,3 - cyclobutylene Carbonate 423 c . Aryl - Alkyl Phthalates ... 425 7. Miscellaneous 426 .... J. Cross - Linked Epoxy Resin Systems References 428 432 Supplemental References A. Styrene ...
... Bisphenol A Carbonate 416 b . Tetramethyl - 1,3 - cyclobutylene Carbonate 423 c . Aryl - Alkyl Phthalates ... 425 7. Miscellaneous 426 .... J. Cross - Linked Epoxy Resin Systems References 428 432 Supplemental References A. Styrene ...
Page 11
... bisphenol - A copolycarbonate OCO ою OCO осо -OC . -осо ою осо осо- Юб Alternating hydroquinone - bisphenol - A copolycarbonate Fig . 2-1 . Random and alternating copolymers . techniques , as well as many step - growth reactions.
... bisphenol - A copolycarbonate OCO ою OCO осо -OC . -осо ою осо осо- Юб Alternating hydroquinone - bisphenol - A copolycarbonate Fig . 2-1 . Random and alternating copolymers . techniques , as well as many step - growth reactions.
Page 12
... bisphenol - A copolycarbonates with an alternating structure ( see Fig . 2-1 ) can be prepared by first forming the dichloroformate of one of the monomers and subsequently condensing this intermediate with the second bisphenol . The ...
... bisphenol - A copolycarbonates with an alternating structure ( see Fig . 2-1 ) can be prepared by first forming the dichloroformate of one of the monomers and subsequently condensing this intermediate with the second bisphenol . The ...
Page 41
... random fashion . This is shown in Scheme 4-8 . A typical example of this is the coupling of hydroxyl - terminated poly ( ethylene oxide ) and bisphenol - A polycarbonate oligomers by CH , HO CH3 -0060-0.00 ) офо CH , CH A. SYNTHESIS 41.
... random fashion . This is shown in Scheme 4-8 . A typical example of this is the coupling of hydroxyl - terminated poly ( ethylene oxide ) and bisphenol - A polycarbonate oligomers by CH , HO CH3 -0060-0.00 ) офо CH , CH A. SYNTHESIS 41.
Page 155
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A-B block A-B-A block copolymers a-methylstyrene adipate anionic behavior bisphenol blends Block and Graft block copolymer structures block copolymers block copolymers containing British Patent butadiene catalyst CH₂ Chapter Chem Chemical compositions copoly copolymerization cross-linked crystalline diisocyanate Dimethylsiloxane diol display domains elastomeric end groups ethylene oxide films French Patent German Offen graft copolymers homopolymers initiation Internationale Research Maatschappij isoprene Japanese Patent Macromolecules Makromol Matzner mechanical properties melting point methacrylate methyl modulus molecular weight monomer morphology Netherlands Patent Appl Noshay oligomers phase Phillips Petroleum Phillips Petroleum Co phosgenation Plast poly(ethylene oxide polyamide polybutadiene polycaprolactone polyester polyether Polym polymerization polypropylene polystyrene polysulfone polyurethanes prepared random copolymers reaction reported Research Maatschappij N.V. Rubber Scheme segments Shell Internationale Research siloxane Soedin solubility solution solvent styrene styrene-butadiene styrene-butadiene-styrene synthesis techniques temperature terephthalate Tetramethylene thermal tion two-phase U.S. Patent urethane viscosity Vysokomol