Block Copolymers: Overview and Critical SurveyBlock Copolymers: Overview and Critical Survey is a critical review of block copolymer technology and a comprehensive critical survey on the synthesis, characterization, properties, and applications of the specific block copolymer structures reported in the literature. The copolymers are organized according to segmental architecture and chemical composition. Comprised of seven chapters, this book begins with an overview of what block copolymers are, how they are made, and what they can and cannot be expected to do. The next chapter defines block copolymers and compares them with other types of polymer "hybrids," that is, polymer blends, random copolymers, and graft copolymers. The various segmental architectures that are possible with block copolymers are then described, followed by a discussion on the various synthesis techniques applicable to block copolymers; the characterization methods capable of elucidating block copolymer structures; some applications of commercially available block copolymers; and some future challenges for block copolymer technology. The last three chapters are devoted to A-B diblock copolymers, A-B-A triblock copolymers, and (A-B)n multiblock copolymers. This monograph should be useful to readers who want to become generally conversant with block copolymer technology and to those who need to delve more deeply into the subject. |
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Page xi
... Styrene - Dienes 228 229 232 4. Other Alkenyl Aromatic - Dienes 235 5. Diene - Dienes 235 6. Styrene - Alkenyl Aromatics 237 B. Polyacrylic and Polyvinylpyridine Block Copolymers . . 238 1. Acrylics 238 2. Vinylpyridine 240 C ...
... Styrene - Dienes 228 229 232 4. Other Alkenyl Aromatic - Dienes 235 5. Diene - Dienes 235 6. Styrene - Alkenyl Aromatics 237 B. Polyacrylic and Polyvinylpyridine Block Copolymers . . 238 1. Acrylics 238 2. Vinylpyridine 240 C ...
Page 33
... styrene and butadiene ( see Chapter 5 , Section A ; Chapter 6 , Section A ) . This technique , which is used mainly with alkenyl aromatic and diene monomers , is carried out by the polymerization of styrene fol- lowed by the sequential ...
... styrene and butadiene ( see Chapter 5 , Section A ; Chapter 6 , Section A ) . This technique , which is used mainly with alkenyl aromatic and diene monomers , is carried out by the polymerization of styrene fol- lowed by the sequential ...
Page 48
... styrene - diene block copolymers prepared by con- trollable anionic living polymer processes , have been subjected to exhaustive structural studies . Most other block copolymers have been assigned structures deduced almost entirely from ...
... styrene - diene block copolymers prepared by con- trollable anionic living polymer processes , have been subjected to exhaustive structural studies . Most other block copolymers have been assigned structures deduced almost entirely from ...
Page 65
... styrene - butadiene - styrene ( A - B - A ) block copolymers ( see Chapter 5 ... diene systems , including polyurethanes , silicones , polyesters , and ... STYRENE POLY- STYRENE POLYBUTADIENE 10-15,000 M.W. 50-70,000 M.W. 10-15,000 C ...
... styrene - butadiene - styrene ( A - B - A ) block copolymers ( see Chapter 5 ... diene systems , including polyurethanes , silicones , polyesters , and ... STYRENE POLY- STYRENE POLYBUTADIENE 10-15,000 M.W. 50-70,000 M.W. 10-15,000 C ...
Page 70
... styrene diene A - B - A or radial block copolymers and their hydrogenated derivatives , i.e. , the Kratons of Shell ... styrene - diene elastomeric block copolymer to be offered commercially was a Solprene styrene - butadiene A - B ...
... styrene diene A - B - A or radial block copolymers and their hydrogenated derivatives , i.e. , the Kratons of Shell ... styrene - diene elastomeric block copolymer to be offered commercially was a Solprene styrene - butadiene A - B ...
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Common terms and phrases
A-B block A-B-A block copolymers a-methylstyrene adipate anionic behavior bisphenol blends Block and Graft block copolymer structures block copolymers block copolymers containing British Patent butadiene catalyst CH₂ Chapter Chem Chemical compositions copoly copolymerization cross-linked crystalline diisocyanate Dimethylsiloxane diol display domains elastomeric end groups ethylene oxide films French Patent German Offen graft copolymers homopolymers initiation Internationale Research Maatschappij isoprene Japanese Patent Macromolecules Makromol Matzner mechanical properties melting point methacrylate methyl modulus molecular weight monomer morphology Netherlands Patent Appl Noshay oligomers phase Phillips Petroleum Phillips Petroleum Co phosgenation Plast poly(ethylene oxide polyamide polybutadiene polycaprolactone polyester polyether Polym polymerization polypropylene polystyrene polysulfone polyurethanes prepared random copolymers reaction reported Research Maatschappij N.V. Rubber Scheme segments Shell Internationale Research siloxane Soedin solubility solution solvent styrene styrene-butadiene styrene-butadiene-styrene synthesis techniques temperature terephthalate Tetramethylene thermal tion two-phase U.S. Patent urethane viscosity Vysokomol