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3-D braid alignment anisotropic applications approximately basal planes bonding borate borate glasses carbon fibers ref carbon matrix Carbon-Carbon Composites CC composites CC materials Chemical Vapor Deposition Composite Materials compressive strength cracks crystallites densification density effective elastic elastic modulus fiber architecture fiber axis fiber bundle fiber surface fiber-reinforced filament geometry graphite heat treatment high modulus high-performance high-temperature impregnation increase interface isotropic knit laminate layer planes matrix matrix composites matrix material mechanical properties mesophase pitch method microcracks microstructure noncircular outer coating oxidation oxygen PAN fibers PAN precursor fiber PAN-based carbon fibers PAN-based fibers percent phenolic pitch matrix pitch-based carbon fibers pitch-based fibers polymer preform pressure produce pyrolysis pyrolytic carbon rayon reinforced resin result shear strength shown in figure stiffness structure substrate techniques temperature tensile modulus tensile strength thermal expansion thermoset thickness transverse unit cell weave woven yarn