## A rheological and structural study of polymer networksContents of this doctoral dissertation include: primary polymer molecules with a mondisperse distribution of the molecular weights, crosslinks of any functionality, primary polymer molecules with a disperse distribution of the molecular weights, the sol fraction, number and weight average degrees of polymerization, Schulz-Zimm distribution, fractions of ideal networks and dangling ends, molar masses between the crosslinks |

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Page 54

Similar to previous publications, these distributions will be referred to with "cum2"

Schulz-

fraction. The fraction of polymer molecules that are not connected to a network ...

Similar to previous publications, these distributions will be referred to with "cum2"

Schulz-

**Flory**and "cum 1.5" Schulz-**Flory**, respectively.'2,5,61 § 2.3.3.1.1 The solfraction. The fraction of polymer molecules that are not connected to a network ...

Page 58

where equation (2.97) has been used also and Asfs must be replaced by Asfi or

A$f\ .5 and Do by 2 or 1.5 if the molecular weight distribution is described with the

"cum2" Schulz-

where equation (2.97) has been used also and Asfs must be replaced by Asfi or

A$f\ .5 and Do by 2 or 1.5 if the molecular weight distribution is described with the

"cum2" Schulz-

**Flory**or the "cum 1.5" Schulz-**Flory**, respectively. The number ...Page 70

Table 2.2 Network model applied to various molecular weight distributions § 2.6

References [ 1 ]

Schulz-FIory [7] 2 Schulz-

[5] ...

Table 2.2 Network model applied to various molecular weight distributions § 2.6

References [ 1 ]

**Flory**, P. J. J. 70. D MWD Reference 1 Monodisperse [7] 1.5Schulz-FIory [7] 2 Schulz-

**Flory**[7] >1 Schulz-Zimm [3] >1.5 "cum 1.5" Schulz-**Flory**[5] ...

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### Contents

_t A Rheological and Structural Study of Polymer Networks | 1 |

Modelling of Polymer Networks | 18 |

Simulations of Polymer Networks | 74 |

Copyright | |

3 other sections not shown

### Common terms and phrases

active network chains average crosslinking index average molar mass average molecular weight calculated complex formation enthalpies constant crosslink functionality crosslinked system crosslinks per unit curves cycle rank dangling ends decrease deformation degree of polymerisation discotic side chain discotic side-chain polymers disperse distribution dynamic elastically active network equilibrium shear modulus figure Flory fraction of dangling fraction of ideal frequency high shear rates hypothetical crosslinking process increase kg/mol mijn molecular weight distribution monodisperse distribution network fraction network of polymer network parameters Nijenhuis number and weight number average degree number average molecular number of crosslinks physical network polydispersity index polymer in 1,1,2-trichloroethane polymeric polyvinyl chloride primary polymer molecules relationship rheological measurements Schulz-Flory distribution Schulz-Zimm distribution side chain polymer sol fraction solubility parameter solution of discotic solvent storage modulus strain structure substituting equation temperature tetrafunctional crosslinking total number unit volume values viscoelastic viscosity w/w solution weight average crosslinking weight average molecular yield stress zijn