Solid State Behavior of Linear Polyesters and Polyamides |
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Page 49
The solid state post - polycondensation rate decreases exponentially as the
temperature decreases still further below the melting temperature ; this was
demonstrated with nylon 6 [ 121 ] and PET ( 106 ] ( Figure 5 ) , but with the latter ,
the ...
The solid state post - polycondensation rate decreases exponentially as the
temperature decreases still further below the melting temperature ; this was
demonstrated with nylon 6 [ 121 ] and PET ( 106 ] ( Figure 5 ) , but with the latter ,
the ...
Page 79
In this case , the ( 100 ) interplanar spacing increases with treatment temperature
, while the ( 010 ) spacing decreases . Elad and Schultz [ 8 ] show that both
interplanar spacings decrease over the first few tens of milliseconds of heat ...
In this case , the ( 100 ) interplanar spacing increases with treatment temperature
, while the ( 010 ) spacing decreases . Elad and Schultz [ 8 ] show that both
interplanar spacings decrease over the first few tens of milliseconds of heat ...
Page 112
In a later study , Prevorsek and Sibilia [ 57 ] found that the fold content decreases
with increasing initial orientation during isochronal heat - treatment at a given
temperature and that the fold content decreases with increasing treatment ...
In a later study , Prevorsek and Sibilia [ 57 ] found that the fold content decreases
with increasing initial orientation during isochronal heat - treatment at a given
temperature and that the fold content decreases with increasing treatment ...
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achieved acid additional amorphous annealing Appl applied aspect average behavior block bonding changes Chem chemical composites conclusion constant crack crystallinity crystallization curves decreases deformation density depends determined diameter diffusion direction distribution domains draw ratio drawn effect element energy Equation experiments extrusion factor fatigue fiber Figure fracture fracture toughness function given groups growth healing heat higher important increasing indicated initial length linear load lower material matrix maximum measurements mechanical melt method microfibrils microstructure modulus molded molecular weight molecules nylon nylon 66 observed obtained occurs orientation peak phase Phys polyamides polycondensation polyesters Polymer Sci polymerization properties range reaction regions reported Reprinted from Ref respectively samples SAXS scattering shows solid solid state polycondensation solid-state specimen speed stage strain strength stress structure studied Table temperature tensile units values yield