Solid State Behavior of Linear Polyesters and Polyamides |
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Page 3
Condensation polymerization , or polycondensation , has been defined by IUPAC
as a polymerization in which small molecules form polymer molecules in a
condensation reaction ; besides polymer molecules , the latter yields other small
...
Condensation polymerization , or polycondensation , has been defined by IUPAC
as a polymerization in which small molecules form polymer molecules in a
condensation reaction ; besides polymer molecules , the latter yields other small
...
Page 11
In these interchange reactions between polymer molecules there is no clear shift
in the number of interunit linkages or the number of molecules on either side of
the equation . The average molecular weight is therefore unaffected by the ...
In these interchange reactions between polymer molecules there is no clear shift
in the number of interunit linkages or the number of molecules on either side of
the equation . The average molecular weight is therefore unaffected by the ...
Page 135
Because of its molecular simplicity and easy experimentability , PE remains the
most investigated fiber , but the ... Indiscernible by X - ray and microscopical
analysis , the existence of these molecules is inferred from mechanical and
thermal ...
Because of its molecular simplicity and easy experimentability , PE remains the
most investigated fiber , but the ... Indiscernible by X - ray and microscopical
analysis , the existence of these molecules is inferred from mechanical and
thermal ...
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achieved acid additional amorphous annealing Appl applied aspect average behavior block bonding changes Chem chemical composites conclusion constant crack crystallinity crystallization curves decreases deformation density depends determined diameter diffusion direction distribution domains draw ratio drawn effect element energy Equation experiments extrusion factor fatigue fiber Figure fracture fracture toughness function given groups growth healing heat higher important increasing indicated initial length linear load lower material matrix maximum measurements mechanical melt method microfibrils microstructure modulus molded molecular weight molecules nylon nylon 66 observed obtained occurs orientation peak phase Phys polyamides polycondensation polyesters Polymer Sci polymerization properties range reaction regions reported Reprinted from Ref respectively samples SAXS scattering shows solid solid state polycondensation solid-state specimen speed stage strain strength stress structure studied Table temperature tensile units values yield