Nanosystems: Molecular Machinery, Manufacturing, and Computation"Devices enormously smaller than before will remodel engineering,chemistry, medicine, and computer technology. How can we understandmachines that are so small? Nanosystems covers it all: powerand strength, friction and wear, thermal noise and quantumuncertainty. This is the book for starting the next century ofengineering." - Marvin Minsky MIT Science magazine calls Eric Drexler "Mr. Nanotechnology."For years, Drexler has stirred controversy by declaring thatmolecular nanotechnology will bring a sweeping technologicalrevolution - delivering tremendous advances in miniaturization,materials, computers, and manufacturing of all kinds. Now, he'swritten a detailed, top-to-bottom analysis of molecular machinery -how to design it, how to analyze it, and how to build it.Nanosystems is the first scientifically detailed description ofdevelopments that will revolutionize most of the industrialprocesses and products currently in use. This groundbreaking work draws on physics and chemistry toestablish basic concepts and analytical tools. The book thendescribes nanomechanical components, devices, and systems,including parallel computers able to execute 1020 instructions persecond and desktop molecular manufacturing systems able to makesuch products. Via chemical and biochemical techniques, proximalprobe instruments, and software for computer-aided moleculardesign, the book charts a path from present laboratory capabilitiesto advanced molecular manufacturing. Bringing together physics,chemistry, mechanical engineering, and computer science,Nanosystems provides an indispensable introduction to theemerging field of molecular nanotechnology. |
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Page 215
... intersystem crossing . Electron spin complicates radical coupling and related reactions . Bond formation demands ... intersystem crossing ) . As the radicals approach , the gap between the triplet and singlet state energies grows , but ...
... intersystem crossing . Electron spin complicates radical coupling and related reactions . Bond formation demands ... intersystem crossing ) . As the radicals approach , the gap between the triplet and singlet state energies grows , but ...
Page 216
... intersystem crossing , at the energetic cost of placing some other portion of the system into a triplet state . If intersystem crossing is required during the transformation time , however , then a condition like Eq . ( 8.12 ) must be ...
... intersystem crossing , at the energetic cost of placing some other portion of the system into a triplet state . If intersystem crossing is required during the transformation time , however , then a condition like Eq . ( 8.12 ) must be ...
Page 224
... intersystem cross- ing , bond cleavage yields a singlet diradical . In a well - separated diradical , how- ever ... crossing , this equilibration process results in AF = -In ( 2 ) kT ( corresponding to the loss of one bit of information ) .
... intersystem cross- ing , bond cleavage yields a singlet diradical . In a well - separated diradical , how- ever ... crossing , this equilibration process results in AF = -In ( 2 ) kT ( corresponding to the loss of one bit of information ) .
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approximation assembly assumed atoms barrier bond carbon Chapter chemical chemistry classical complex components compression computational constraints continuum models covalent density described devices diamond diamondoid structures discussed displacement drive effects elastic electronic electrostatic energy dissipation engineering entropy equilibrium estimated Figure force free energy frequency function gears geometry hydrogen input interactions interface intersystem crossing knob ligand logic rod macroscale magnitude manufacturing systems mass mechanochemical mechanosynthesis modulus moieties molecular manufacturing molecular mechanics molecular nanotechnology molecules motion nanomechanical systems nanometer nanoscale nonbonded nonbonded interactions operations oscillator parameters phonon pi bond position potential energy potential energy surface protein quantum mechanical radiation radical range rates reaction reactive reagent reagent moieties receptor resulting rotation scale Section shear sigma bonds sliding solution-phase specific speed stability statistical mechanics steric stiffness substantial surface synthesis temperature theoretical applied science thermal tion transition transition state theory typical values vibrational volume yields