Polymer Networks: Principles of Their Formation, Structure and PropertiesR.F. Stepto Written by an international team of authors with a strong emphasis on the underlying chemistry, this book forms a timely, concise, and accessible evaluation of the fundamentals of polymer network formation, structure, and properties, and how these three aspects are interrelated. |
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Results 1-3 of 45
Page 189
... components are compatible . Thus , only the elastic free - energy density of the subnetworks , Fsub , and the ... component I ( I = A , B , ... ) occupies an average volume fraction f , subject to fi = 1. The thermo- dynamic observables ...
... components are compatible . Thus , only the elastic free - energy density of the subnetworks , Fsub , and the ... component I ( I = A , B , ... ) occupies an average volume fraction f , subject to fi = 1. The thermo- dynamic observables ...
Page 193
... components [ 22 ] . Figure 6.1 shows the time t * for the formation of an IPN , created by simultaneous polymerization of tetrafunc- tional ( component A , reaction - rate constant k ) and trifunctional ( component B , reaction - rate ...
... components [ 22 ] . Figure 6.1 shows the time t * for the formation of an IPN , created by simultaneous polymerization of tetrafunc- tional ( component A , reaction - rate constant k ) and trifunctional ( component B , reaction - rate ...
Page 232
... components correspond to shear stresses . In the particular case when the shear stresses equate to zero , the normal stresses are referred to as the principal stresses . In the following sections only simple tension or com- pression ...
... components correspond to shear stresses . In the particular case when the shear stresses equate to zero , the normal stresses are referred to as the principal stresses . In the following sections only simple tension or com- pression ...
Contents
Contents | 1 |
Nonlinear polymerization gelation and network formation | 14 |
4 | 40 |
Copyright | |
14 other sections not shown
Common terms and phrases
behaviour block copolymers Chapter Chem chemical components composition concentration constant conversion copolymerization crosslinking CTT diagram cure curve cyclization decrease deformation degree of polymerization dependence distribution Dušek EANCS Eichinger elastomers endlinking entanglements equation equilibrium Erman experimental Flory formed Frisch gel point gelation hard segments hard-segment content Ilavský increase initial injection moulding intramolecular reaction junction points kinetics linear Macosko Macromol Macromolecules mechanical microphase separation modulus molar mass molecular weight molecules monomer mould network chains network formation network materials network structure network-forming occur parameter phase separation Phys polymer networks Polymer Sci polyurethane predicted primary chains properties PUr-DETDA RA₂ ratio reactants reacted reactive groups RIM copolymer RIM materials ring structures rubber sample shear modulus shown in Figure soft segments soft-segment spinodal spinodal decomposition Stepto stress-strain Tcure temperature tensile thermodynamic thermosetting triol units values versus viscoelastic viscosity vitrification vitrification region volume fraction